Hydrothermal synthesis and characterization of a new 3D iron phosphatooxalate templated by organo-amine

He Meng; Guang Hua Li; Yan Xing; Yu Lin Yang; Yan Jie Cui; Li Liu; Hong Ding; Wen Qin Pang

doi:10.1016/j.poly.2004.07.016

Hydrothermal synthesis and characterization of a new 3D iron phosphatooxalate templated by organo-amine

He Meng
, Guang Hua Li
, Yan Xing
, Yu Lin Yang
, Yan Jie Cui
, Li Liu
, Hong Ding
, Wen Qin Pang

College of Chemistry

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

A new organically templated iron(II) phosphatooxalate, (N₂C ₄H₁₂)[Fe₄(C₂O₄) ₃(HPO₄)₂(H₂O)], I has been synthesized under hydrothermal conditions, in which oxalate groups act as bidentate ligands to Fe and hold the structure together by strong interlayer Pa-Oa-H-oxalate hydrogen bonds. A new organically templated iron(II) phosphatooxalate, (N₂C₄H₁₂)[Fe ₄(C₂O₄)₃(HPO₄) ₂(H₂O)₂] I, has been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction. The structure possesses infinite chains made from Fe₂O₁₀ dimers and PO₄ tetrahedra bridged by bidentate oxalate units and strong interlayer Pa-Oa-H-oxalate hydrogen bonds. The diprotonated piperazinium cations are located in the intersecting tunnels parallel to the [1 0 0] and [0 1 0] directions.

Original language	English
Pages (from-to)	2357-2362
Number of pages	6
Journal	Polyhedron
Volume	23
Issue number	15
DOIs	https://doi.org/10.1016/j.poly.2004.07.016
State	Published - 30 Sep 2004
Externally published	Yes

Keywords

Crystal structure
Hydrothermal synthesis
Iron phosphatooxalate
Oxalate acid
Piperazine
Template

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10.1016/j.poly.2004.07.016

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@article{65f0df454e3a41c18b1cf96b7844e723,

title = "Hydrothermal synthesis and characterization of a new 3D iron phosphatooxalate templated by organo-amine",

abstract = "A new organically templated iron(II) phosphatooxalate, (N2C 4H12)[Fe4(C2O4) 3(HPO4)2(H2O)], I has been synthesized under hydrothermal conditions, in which oxalate groups act as bidentate ligands to Fe and hold the structure together by strong interlayer Pa-Oa-H-oxalate hydrogen bonds. A new organically templated iron(II) phosphatooxalate, (N2C4H12)[Fe 4(C2O4)3(HPO4) 2(H2O)2] I, has been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction. The structure possesses infinite chains made from Fe2O10 dimers and PO4 tetrahedra bridged by bidentate oxalate units and strong interlayer Pa-Oa-H-oxalate hydrogen bonds. The diprotonated piperazinium cations are located in the intersecting tunnels parallel to the [1 0 0] and [0 1 0] directions.",

keywords = "Crystal structure, Hydrothermal synthesis, Iron phosphatooxalate, Oxalate acid, Piperazine, Template",

author = "He Meng and Li, \{Guang Hua\} and Yan Xing and Yang, \{Yu Lin\} and Cui, \{Yan Jie\} and Li Liu and Hong Ding and Pang, \{Wen Qin\}",

year = "2004",

month = sep,

day = "30",

doi = "10.1016/j.poly.2004.07.016",

language = "英语",

volume = "23",

pages = "2357--2362",

journal = "Polyhedron",

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TY - JOUR

T1 - Hydrothermal synthesis and characterization of a new 3D iron phosphatooxalate templated by organo-amine

AU - Meng, He

AU - Li, Guang Hua

AU - Xing, Yan

AU - Yang, Yu Lin

AU - Cui, Yan Jie

AU - Liu, Li

AU - Ding, Hong

AU - Pang, Wen Qin

PY - 2004/9/30

Y1 - 2004/9/30

N2 - A new organically templated iron(II) phosphatooxalate, (N2C 4H12)[Fe4(C2O4) 3(HPO4)2(H2O)], I has been synthesized under hydrothermal conditions, in which oxalate groups act as bidentate ligands to Fe and hold the structure together by strong interlayer Pa-Oa-H-oxalate hydrogen bonds. A new organically templated iron(II) phosphatooxalate, (N2C4H12)[Fe 4(C2O4)3(HPO4) 2(H2O)2] I, has been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction. The structure possesses infinite chains made from Fe2O10 dimers and PO4 tetrahedra bridged by bidentate oxalate units and strong interlayer Pa-Oa-H-oxalate hydrogen bonds. The diprotonated piperazinium cations are located in the intersecting tunnels parallel to the [1 0 0] and [0 1 0] directions.

AB - A new organically templated iron(II) phosphatooxalate, (N2C 4H12)[Fe4(C2O4) 3(HPO4)2(H2O)], I has been synthesized under hydrothermal conditions, in which oxalate groups act as bidentate ligands to Fe and hold the structure together by strong interlayer Pa-Oa-H-oxalate hydrogen bonds. A new organically templated iron(II) phosphatooxalate, (N2C4H12)[Fe 4(C2O4)3(HPO4) 2(H2O)2] I, has been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction. The structure possesses infinite chains made from Fe2O10 dimers and PO4 tetrahedra bridged by bidentate oxalate units and strong interlayer Pa-Oa-H-oxalate hydrogen bonds. The diprotonated piperazinium cations are located in the intersecting tunnels parallel to the [1 0 0] and [0 1 0] directions.

KW - Crystal structure

KW - Hydrothermal synthesis

KW - Iron phosphatooxalate

KW - Oxalate acid

KW - Piperazine

KW - Template

UR - https://www.scopus.com/pages/publications/5344233427

U2 - 10.1016/j.poly.2004.07.016

DO - 10.1016/j.poly.2004.07.016

M3 - 文章

AN - SCOPUS:5344233427

SN - 0277-5387

VL - 23

SP - 2357

EP - 2362

JO - Polyhedron

JF - Polyhedron

IS - 15

ER -

Hydrothermal synthesis and characterization of a new 3D iron phosphatooxalate templated by organo-amine

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