Hydrothermal syntheses, crystal structures and thermal properties of two new organically templated open-framework gallium phosphites

Guang peng Zhou; Yu lin Yang; Rui qing Fan; Jia qing Xie; Xue jun Quan

doi:10.1007/s40242-013-2212-x

Hydrothermal syntheses, crystal structures and thermal properties of two new organically templated open-framework gallium phosphites

Guang peng Zhou
, Yu lin Yang
, Rui qing Fan
, Jia qing Xie
, Xue jun Quan

School of Chemistry and Chemical Engineering

Harbin Institute of Technology
Chongqing Institute of Technology

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

Two new open-framework gallium phosphites formulated as (C₂N₂H₁₀)_0.5Ga₂(OH)(H₂O)(HPO₃)₃(1) and (C₃N₂H₅)₂(C₃N₂H₆)Ga₈(H₂O)₆(HPO₃)₁₄(2) were hydrothermally synthesized in the presence of ethylenediamine(en) and imidazole as structure directing agents(SDA), respectively. Structural analyses reveal that the 3D structures of compounds 1 and 2 are both built up from the linkage of GaO₆, GaO₅(H₂O) and HPO₃ ^2- units by sharing vertices. The structure of compound 2 is constructed from well-known 4.6.12-net connecting layers in the AAAA stacking sequence, which are penetrated by the 1D Ga-O-P chains to form a 3D pillared-layered structure.

Original language	English
Pages (from-to)	201-205
Number of pages	5
Journal	Chemical Research in Chinese Universities
Volume	29
Issue number	2
DOIs	https://doi.org/10.1007/s40242-013-2212-x
State	Published - Apr 2013

Keywords

Crystal structure
Gallium phosphite
Hydrothermal synthesis

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10.1007/s40242-013-2212-x

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title = "Hydrothermal syntheses, crystal structures and thermal properties of two new organically templated open-framework gallium phosphites",

abstract = "Two new open-framework gallium phosphites formulated as (C2N2H10)0.5Ga2(OH)(H2O)(HPO3)3(1) and (C3N2H5)2(C3N2H6)Ga8(H2O)6(HPO3)14(2) were hydrothermally synthesized in the presence of ethylenediamine(en) and imidazole as structure directing agents(SDA), respectively. Structural analyses reveal that the 3D structures of compounds 1 and 2 are both built up from the linkage of GaO6, GaO5(H2O) and HPO3 2- units by sharing vertices. The structure of compound 2 is constructed from well-known 4.6.12-net connecting layers in the AAAA stacking sequence, which are penetrated by the 1D Ga-O-P chains to form a 3D pillared-layered structure.",

keywords = "Crystal structure, Gallium phosphite, Hydrothermal synthesis",

author = "Zhou, \{Guang peng\} and Yang, \{Yu lin\} and Fan, \{Rui qing\} and Xie, \{Jia qing\} and Quan, \{Xue jun\}",

year = "2013",

month = apr,

doi = "10.1007/s40242-013-2212-x",

language = "英语",

volume = "29",

pages = "201--205",

journal = "Chemical Research in Chinese Universities",

issn = "1005-9040",

publisher = "Springer Science and Business Media Deutschland GmbH",

number = "2",

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TY - JOUR

T1 - Hydrothermal syntheses, crystal structures and thermal properties of two new organically templated open-framework gallium phosphites

AU - Zhou, Guang peng

AU - Yang, Yu lin

AU - Fan, Rui qing

AU - Xie, Jia qing

AU - Quan, Xue jun

PY - 2013/4

Y1 - 2013/4

N2 - Two new open-framework gallium phosphites formulated as (C2N2H10)0.5Ga2(OH)(H2O)(HPO3)3(1) and (C3N2H5)2(C3N2H6)Ga8(H2O)6(HPO3)14(2) were hydrothermally synthesized in the presence of ethylenediamine(en) and imidazole as structure directing agents(SDA), respectively. Structural analyses reveal that the 3D structures of compounds 1 and 2 are both built up from the linkage of GaO6, GaO5(H2O) and HPO3 2- units by sharing vertices. The structure of compound 2 is constructed from well-known 4.6.12-net connecting layers in the AAAA stacking sequence, which are penetrated by the 1D Ga-O-P chains to form a 3D pillared-layered structure.

AB - Two new open-framework gallium phosphites formulated as (C2N2H10)0.5Ga2(OH)(H2O)(HPO3)3(1) and (C3N2H5)2(C3N2H6)Ga8(H2O)6(HPO3)14(2) were hydrothermally synthesized in the presence of ethylenediamine(en) and imidazole as structure directing agents(SDA), respectively. Structural analyses reveal that the 3D structures of compounds 1 and 2 are both built up from the linkage of GaO6, GaO5(H2O) and HPO3 2- units by sharing vertices. The structure of compound 2 is constructed from well-known 4.6.12-net connecting layers in the AAAA stacking sequence, which are penetrated by the 1D Ga-O-P chains to form a 3D pillared-layered structure.

KW - Crystal structure

KW - Gallium phosphite

KW - Hydrothermal synthesis

UR - https://www.scopus.com/pages/publications/84882803409

U2 - 10.1007/s40242-013-2212-x

DO - 10.1007/s40242-013-2212-x

M3 - 文章

AN - SCOPUS:84882803409

SN - 1005-9040

VL - 29

SP - 201

EP - 205

JO - Chemical Research in Chinese Universities

JF - Chemical Research in Chinese Universities

IS - 2

ER -

Hydrothermal syntheses, crystal structures and thermal properties of two new organically templated open-framework gallium phosphites

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Keywords

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