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Hydrogen-bonded assemblies of a new polyoxometalate-based 3-D supramolecular architecture

  • Zhihui Yi
  • , Xiao Zhang*
  • , Xiaoyang Yu
  • , Lei Liu
  • , Xianzhu Xu
  • , Xiaobing Cui
  • , Jiqing Xu
  • *Corresponding author for this work
  • Harbin Institute of Technology
  • Jilin Institute of Chemical Technology
  • College of Chemistry

Research output: Contribution to journalArticlepeer-review

Abstract

A new hydrogen-bonded 3-D supramolecular architecture [Ni(2,2'-bpy) 3]1.5[AsWVI 10WV 2O40Ni (2,2'-bpy)2(H2O)]0.5H2O (2,2'-bpy = 2,2'-bipyridine) (1) has been hydrothermally synthesized and characterized by single-crystal X-ray diffraction analysis, PXRD, elemental analysis, XPS, and IR spectrum. Compound 1 exhibits photocatalytic activity for methylene blue degradation under visible- light irradiation and shows good stability toward visible-light photocatalysis. Luminescence of 1 is also reported.

Original languageEnglish
Pages (from-to)1876-1888
Number of pages13
JournalJournal of Coordination Chemistry
Volume66
Issue number11
DOIs
StatePublished - 2013

Keywords

  • Crystal structure
  • Fluorescence
  • Hydrogen-bonded
  • Photocatalytic activity
  • Supramolecular network

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