Hydrogen bond and 3D frameworks to reconcile the conflict between safety and detonation performance in energetic metal–organic frameworks

Jinhao Zhang; Zhicheng Guo; Yulan Song; Wenjia Hao; Rufang Peng; Bo Jin

doi:10.1016/j.cej.2022.139762

Hydrogen bond and 3D frameworks to reconcile the conflict between safety and detonation performance in energetic metal–organic frameworks

Jinhao Zhang
, Zhicheng Guo
, Yulan Song
, Wenjia Hao
, Rufang Peng
, Bo Jin^*

^*Corresponding author for this work

Southwest University of Science and Technology

Research output: Contribution to journal › Article › peer-review

34 Scopus citations

Abstract

Energetic metal–organic frameworks (EMOFs), which combine energetic ligands with metal ions, hold promise as novel energetic materials to balance the sensitivity and safety of explosives. The coordinating solvent molecules have a significant effect on the energetic properties of EMOFs. Two EMOFs, [K(AFTO)·H₂O]_n (1) and solvent-free [K(AFTO)]_n (2), were obtained at different reaction temperatures. EMOFs 1 and 2 exhibit excellent thermal stability (T_d,₁ = 569 K, T_d,₂ = 574 K), insensitivity to mechanical stimuli (FS ≥ 360 N, IS ≥ 40 J for 1; FS ≥ 360 N, IS = 35 J for 2) and satisfactory detonation performance (D₁ = 8291 m s⁻¹, P₁ = 31.9 GPa; D₂ = 8415 m s⁻¹, P₂ = 32.7 GPa) due to their different 3D framework structures and strong hydrogen bond networks.

Original language	English
Article number	139762
Journal	Chemical Engineering Journal
Volume	453
DOIs	https://doi.org/10.1016/j.cej.2022.139762
State	Published - 1 Feb 2023
Externally published	Yes

Keywords

3D EMOFs
AFTO
Energetic materials
Hydrogen bond
Potassium
Solvent-free

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10.1016/j.cej.2022.139762

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title = "Hydrogen bond and 3D frameworks to reconcile the conflict between safety and detonation performance in energetic metal–organic frameworks",

abstract = "Energetic metal–organic frameworks (EMOFs), which combine energetic ligands with metal ions, hold promise as novel energetic materials to balance the sensitivity and safety of explosives. The coordinating solvent molecules have a significant effect on the energetic properties of EMOFs. Two EMOFs, [K(AFTO)·H2O]n (1) and solvent-free [K(AFTO)]n (2), were obtained at different reaction temperatures. EMOFs 1 and 2 exhibit excellent thermal stability (Td,1 = 569 K, Td,2 = 574 K), insensitivity to mechanical stimuli (FS ≥ 360 N, IS ≥ 40 J for 1; FS ≥ 360 N, IS = 35 J for 2) and satisfactory detonation performance (D1 = 8291 m s−1, P1 = 31.9 GPa; D2 = 8415 m s−1, P2 = 32.7 GPa) due to their different 3D framework structures and strong hydrogen bond networks.",

keywords = "3D EMOFs, AFTO, Energetic materials, Hydrogen bond, Potassium, Solvent-free",

author = "Jinhao Zhang and Zhicheng Guo and Yulan Song and Wenjia Hao and Rufang Peng and Bo Jin",

note = "Publisher Copyright: {\textcopyright} 2022",

year = "2023",

month = feb,

day = "1",

doi = "10.1016/j.cej.2022.139762",

language = "英语",

volume = "453",

journal = "Chemical Engineering Journal",

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TY - JOUR

T1 - Hydrogen bond and 3D frameworks to reconcile the conflict between safety and detonation performance in energetic metal–organic frameworks

AU - Zhang, Jinhao

AU - Guo, Zhicheng

AU - Song, Yulan

AU - Hao, Wenjia

AU - Peng, Rufang

AU - Jin, Bo

PY - 2023/2/1

Y1 - 2023/2/1

N2 - Energetic metal–organic frameworks (EMOFs), which combine energetic ligands with metal ions, hold promise as novel energetic materials to balance the sensitivity and safety of explosives. The coordinating solvent molecules have a significant effect on the energetic properties of EMOFs. Two EMOFs, [K(AFTO)·H2O]n (1) and solvent-free [K(AFTO)]n (2), were obtained at different reaction temperatures. EMOFs 1 and 2 exhibit excellent thermal stability (Td,1 = 569 K, Td,2 = 574 K), insensitivity to mechanical stimuli (FS ≥ 360 N, IS ≥ 40 J for 1; FS ≥ 360 N, IS = 35 J for 2) and satisfactory detonation performance (D1 = 8291 m s−1, P1 = 31.9 GPa; D2 = 8415 m s−1, P2 = 32.7 GPa) due to their different 3D framework structures and strong hydrogen bond networks.

AB - Energetic metal–organic frameworks (EMOFs), which combine energetic ligands with metal ions, hold promise as novel energetic materials to balance the sensitivity and safety of explosives. The coordinating solvent molecules have a significant effect on the energetic properties of EMOFs. Two EMOFs, [K(AFTO)·H2O]n (1) and solvent-free [K(AFTO)]n (2), were obtained at different reaction temperatures. EMOFs 1 and 2 exhibit excellent thermal stability (Td,1 = 569 K, Td,2 = 574 K), insensitivity to mechanical stimuli (FS ≥ 360 N, IS ≥ 40 J for 1; FS ≥ 360 N, IS = 35 J for 2) and satisfactory detonation performance (D1 = 8291 m s−1, P1 = 31.9 GPa; D2 = 8415 m s−1, P2 = 32.7 GPa) due to their different 3D framework structures and strong hydrogen bond networks.

KW - 3D EMOFs

KW - AFTO

KW - Energetic materials

KW - Hydrogen bond

KW - Potassium

KW - Solvent-free

UR - https://www.scopus.com/pages/publications/85140474868

U2 - 10.1016/j.cej.2022.139762

DO - 10.1016/j.cej.2022.139762

M3 - 文章

AN - SCOPUS:85140474868

SN - 1385-8947

VL - 453

JO - Chemical Engineering Journal

JF - Chemical Engineering Journal

M1 - 139762

ER -

Hydrogen bond and 3D frameworks to reconcile the conflict between safety and detonation performance in energetic metal–organic frameworks

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Keywords

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