Highly stereoselective synthesis of trans-alkenes via electrochemical Ni-catalyzed hydroarylation of alkynes with aryl iodides

Haoxiang Zhang; Lin Guo; Chao Yang; Wujiong Xia

doi:10.1039/d3ob00705g

Highly stereoselective synthesis of trans-alkenes via electrochemical Ni-catalyzed hydroarylation of alkynes with aryl iodides

Haoxiang Zhang
, Lin Guo
, Chao Yang^*
, Wujiong Xia^*

^*Corresponding author for this work

Harbin Institute of Technology
Henan Normal University

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

An electrochemical nickel catalyzed hydroarylation reaction of various alkynes is herein described. In this reaction, alkynes were coupled with aryl iodides by electrochemical Ni catalysis to obtain highly selective trans-olefins. The outstanding features of this protocol include mild reaction conditions, operational simplicity, and excellent functional group tolerance.

Original language	English
Pages (from-to)	5189-5193
Number of pages	5
Journal	Organic and Biomolecular Chemistry
Volume	21
Issue number	25
DOIs	https://doi.org/10.1039/d3ob00705g
State	Published - 12 Jun 2023
Externally published	Yes

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title = "Highly stereoselective synthesis of trans-alkenes via electrochemical Ni-catalyzed hydroarylation of alkynes with aryl iodides",

abstract = "An electrochemical nickel catalyzed hydroarylation reaction of various alkynes is herein described. In this reaction, alkynes were coupled with aryl iodides by electrochemical Ni catalysis to obtain highly selective trans-olefins. The outstanding features of this protocol include mild reaction conditions, operational simplicity, and excellent functional group tolerance.",

author = "Haoxiang Zhang and Lin Guo and Chao Yang and Wujiong Xia",

note = "Publisher Copyright: {\textcopyright} 2023 The Royal Society of Chemistry.",

year = "2023",

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day = "12",

doi = "10.1039/d3ob00705g",

language = "英语",

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T1 - Highly stereoselective synthesis of trans-alkenes via electrochemical Ni-catalyzed hydroarylation of alkynes with aryl iodides

AU - Zhang, Haoxiang

AU - Guo, Lin

AU - Yang, Chao

AU - Xia, Wujiong

PY - 2023/6/12

Y1 - 2023/6/12

N2 - An electrochemical nickel catalyzed hydroarylation reaction of various alkynes is herein described. In this reaction, alkynes were coupled with aryl iodides by electrochemical Ni catalysis to obtain highly selective trans-olefins. The outstanding features of this protocol include mild reaction conditions, operational simplicity, and excellent functional group tolerance.

AB - An electrochemical nickel catalyzed hydroarylation reaction of various alkynes is herein described. In this reaction, alkynes were coupled with aryl iodides by electrochemical Ni catalysis to obtain highly selective trans-olefins. The outstanding features of this protocol include mild reaction conditions, operational simplicity, and excellent functional group tolerance.

UR - https://www.scopus.com/pages/publications/85163494382

U2 - 10.1039/d3ob00705g

DO - 10.1039/d3ob00705g

M3 - 文章

C2 - 37323066

AN - SCOPUS:85163494382

SN - 1477-0520

VL - 21

SP - 5189

EP - 5193

JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

IS - 25

ER -

Highly stereoselective synthesis of trans-alkenes via electrochemical Ni-catalyzed hydroarylation of alkynes with aryl iodides

Abstract

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