Highly sensitive CH₄, C₂H₂and CO simultaneous measurement LITES sensor based on multi-pass cell with overlapped spots pattern and QTFs with low resonant frequency

This paper presents a simultaneous measurement light-induced thermoelectric spectroscopy (LITES) sensor with high sensitivity for detecting methane (CH4), carbon monoxide (CO) and acetylene (C2H2). It employs a multi-pass cell (MPC) with an overlapped spots pattern and low resonant frequency circle-head quartz tuning forks (QTFs) for the first time. The fiber-coupled MPC with an optical length (OPL) of 40 m was combined with a thin-film filter (TFF) to improve the laser absorption and enable light spots multiplexing on mirrors. Three self-designed circle-head QTFs with low resonant frequencies of less than 10 kHz and a quality factor of ∼ 11500 were adopted to improve the detection ability. The LITES sensor detected multi-gas signals based on their unique absorption spectrum, enabling real-simultaneous measurement of CH4, CO, and C2H2. After optimization, the minimum detection limits (MDLs) of 0.5 ppm, 126.9 ppm and 0.4 ppm for these gases were obtained, respectively. With integration times of 300 s for CH4 and 200 s each for CO and C2H2, the MDLs could be further reduced to 0.09 ppm, 57.1 ppm, and 0.07 ppm, correspondingly. The paper concludes with a discussion of potential strategies for further improving the performance of such LITES sensors.