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High temperature oxidation and hot corrosion behaviors of PEO and PEO/polysilazane preceramic-based dual-layer coatings on Ti6Al4V alloy

  • Helmholtz-Zentrum Hereon
  • Harbin Institute of Technology
  • Tsinghua University
  • Kiel University

Research output: Contribution to journalArticlepeer-review

Abstract

The high temperature oxidation and corrosion behaviors of a plasma electrolytic oxidation (PEO) coating and a PEO/polysilazane (PEO/PSZ) dual-layer coating are investigated. After exposure in NaCl+Na2SO4 salt at 600 ℃ for 240 h, PEO coating tends to generate porous and loose scales, causing cracking or even complete peeling off from the substrate, and corrosion scales follow the law of formation-shedding-reformulation. After exposure in NaCl+Na2SO4 salt at 600 ℃ for 480 h, the PEO/PSZ coating exhibits a three-layer structure including the outermost corroded layer with sandwich structures, uncorroded Al2O3 particles-containing interlayer, and PEO bottom layer, which retards the continuous penetration of corrosive media and further diffusion of oxygen to the inner bulk alloy, resulting in a remarkable reduction of oxidation and corrosion rate.

Original languageEnglish
Article number111076
JournalCorrosion Science
Volume216
DOIs
StatePublished - 15 May 2023

Keywords

  • Failure mechanism
  • High temperature corrosion
  • Plasma electrolytic oxidation
  • Polysilazane preceramic
  • Ti6Al4V alloy

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