High-temperature electrochemical synthesis of tantalum diboride in chloride-fluoride-melts

S. V. Devyatkin; V. I. Taranenko; Kh B. Kushkhov; V. I. Shapoval

High-temperature electrochemical synthesis of tantalum diboride in chloride-fluoride-melts

S. V. Devyatkin^*
, V. I. Taranenko
, Kh B. Kushkhov
, V. I. Shapoval

^*Corresponding author for this work

NASU - Vernadsky Institute General and Inorganic Chemistry

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

Conditions are given for the TaB₂ electrochemical synthesis from such salt melts as equimolar NaCl-KCl mixtures with K₂TaF₇, KBF₄ and KF(NaF) added at 973 K. The processes occurring in the system result from the formation of Ta and B chloride-fluoride complexes in melts. Controlling the anion composition of an electrolyzer, one can choice conditions for 'thermodynamic' mode of the synthesis. It is carried out in a sealed glass carbon electrolyzer lined with metallic Ta serving as an anode. Glass carbon, steel 3, Nb, Mo are used as a material for the cathode. With the electrolyzer temperature of 973-1023 K and the cathode density of 5×10^-2-2×10^-1 A/cm² dense TaB₂ coats have been obtained on steel 3 and Nb.

Original language	English
Pages (from-to)	71-73
Number of pages	3
Journal	Rasplavy
Issue number	2
State	Published - Mar 1992
Externally published	Yes

Cite this

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title = "High-temperature electrochemical synthesis of tantalum diboride in chloride-fluoride-melts",

abstract = "Conditions are given for the TaB2 electrochemical synthesis from such salt melts as equimolar NaCl-KCl mixtures with K2TaF7, KBF4 and KF(NaF) added at 973 K. The processes occurring in the system result from the formation of Ta and B chloride-fluoride complexes in melts. Controlling the anion composition of an electrolyzer, one can choice conditions for 'thermodynamic' mode of the synthesis. It is carried out in a sealed glass carbon electrolyzer lined with metallic Ta serving as an anode. Glass carbon, steel 3, Nb, Mo are used as a material for the cathode. With the electrolyzer temperature of 973-1023 K and the cathode density of 5×10-2-2×10-1 A/cm2 dense TaB2 coats have been obtained on steel 3 and Nb.",

author = "Devyatkin, \{S. V.\} and Taranenko, \{V. I.\} and Kushkhov, \{Kh B.\} and Shapoval, \{V. I.\}",

year = "1992",

month = mar,

language = "英语",

pages = "71--73",

journal = "Rasplavy",

issn = "0235-0106",

publisher = "Nauka Ekatarinburg",

number = "2",

}

TY - JOUR

T1 - High-temperature electrochemical synthesis of tantalum diboride in chloride-fluoride-melts

AU - Devyatkin, S. V.

AU - Taranenko, V. I.

AU - Kushkhov, Kh B.

AU - Shapoval, V. I.

PY - 1992/3

Y1 - 1992/3

N2 - Conditions are given for the TaB2 electrochemical synthesis from such salt melts as equimolar NaCl-KCl mixtures with K2TaF7, KBF4 and KF(NaF) added at 973 K. The processes occurring in the system result from the formation of Ta and B chloride-fluoride complexes in melts. Controlling the anion composition of an electrolyzer, one can choice conditions for 'thermodynamic' mode of the synthesis. It is carried out in a sealed glass carbon electrolyzer lined with metallic Ta serving as an anode. Glass carbon, steel 3, Nb, Mo are used as a material for the cathode. With the electrolyzer temperature of 973-1023 K and the cathode density of 5×10-2-2×10-1 A/cm2 dense TaB2 coats have been obtained on steel 3 and Nb.

AB - Conditions are given for the TaB2 electrochemical synthesis from such salt melts as equimolar NaCl-KCl mixtures with K2TaF7, KBF4 and KF(NaF) added at 973 K. The processes occurring in the system result from the formation of Ta and B chloride-fluoride complexes in melts. Controlling the anion composition of an electrolyzer, one can choice conditions for 'thermodynamic' mode of the synthesis. It is carried out in a sealed glass carbon electrolyzer lined with metallic Ta serving as an anode. Glass carbon, steel 3, Nb, Mo are used as a material for the cathode. With the electrolyzer temperature of 973-1023 K and the cathode density of 5×10-2-2×10-1 A/cm2 dense TaB2 coats have been obtained on steel 3 and Nb.

UR - https://www.scopus.com/pages/publications/0026837263

M3 - 文章

AN - SCOPUS:0026837263

SN - 0235-0106

SP - 71

EP - 73

JO - Rasplavy

JF - Rasplavy

IS - 2

ER -

High-temperature electrochemical synthesis of tantalum diboride in chloride-fluoride-melts

Abstract

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