Abstract
Layered cobalt oxides, NaxCoO2, with the density of sodium ions, x, ranging from 0.65 to 0.85, were prepared by rapid heat-up method. The determination by X-ray diffraction pattern of crystal structure and the grain morphology studied by scanning electron microscopy were reported. The measurements of electrical conductivity and thermoelectric power were carried out between 300 K and 1100 K. It has been found that the concentration of sodium ions sandwiched between two neighboring CoO2 layers plays a crucial role in transport properties.
| Original language | English |
|---|---|
| Pages (from-to) | 2308-2312 |
| Number of pages | 5 |
| Journal | Solid State Ionics |
| Volume | 179 |
| Issue number | 39 |
| DOIs | |
| State | Published - 15 Dec 2008 |
Keywords
- Sodium ions
- Structure refinement
- Transport properties
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