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High catalytic activity of Fe (III)-substituted aluminophosphate molecular sieves (FeAPO) in oxidation of aromatic compounds

  • X. Meng
  • , Y. Yu
  • , L. Zhao
  • , J. Sun
  • , K. Lin
  • , M. Yang
  • , D. Jiang
  • , S. Qiu
  • , F. S. Xiao*
  • *Corresponding author for this work
  • Jilin University

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

Abstract

Iron substituted aluminophosphate molecular sieves (Fe-AlPO4-11, Fe-AlPO4-5 and Fe-VPI-5) are catalytically active in the oxidations of aromatic compounds such as hydroxylation of phenol, benzene, and naphthol, as well as epoxidation of styrene. The activities of Fe-AlPO4-11, Fe-AlPO4-5 are comparable with that of TS-1 in the oxidation of aromatic compounds. Fe-VPI-5 exhibits high activity in naphthol hydroxylation by H2O2, while TS-1 is completely inactive due to the small pore size. Compared to various catalysts, Fe (III) in the framework is considered to be the major active site in the catalytic reactions. This is an abstract of a paper presented at the 13th International Zeolite Conference (Montpellier, France 7/8-13/2001).

Original languageEnglish
Title of host publicationZeolites and Mesoporous Materials at the dawn of the 21st century, Proceedings of the 13 International Zeolite Conference, 2001
EditorsF. Fajula, F. Di Renzo, A. Galarneau, J. Vedrine
PublisherElsevier Inc.
Pages365
Number of pages1
ISBN (Print)9780444502384
DOIs
StatePublished - 2001
Externally publishedYes
EventZeolites and Mesoporous Materials at the dawn of the 21st century, Proceedings of the 13 International Zeolite Conference, 2001 - Montpellier, France
Duration: 8 Jun 200113 Jun 2001

Publication series

NameStudies in Surface Science and Catalysis
Volume135
ISSN (Print)0167-2991

Conference

ConferenceZeolites and Mesoporous Materials at the dawn of the 21st century, Proceedings of the 13 International Zeolite Conference, 2001
Country/TerritoryFrance
CityMontpellier
Period8/06/0113/06/01

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