Hierarchical NiCo-LDH/NiCoP@NiMn-LDH hybrid electrodes on carbon cloth for excellent supercapacitors

To realize high-performance and long life span supercapacitors, highly electrochemically active materials and rational design of structure are highly desirable. Herein, a hierarchical NiCo-LDH/NiCoP@NiMn-LDH hybrid electrode (NCLP@NiMn-LDH) was synthesized on carbon cloth via a hydrothermal reaction and phosphorization treatment. Owing to the introduction of NiCoP and design of the core-shell structure, the hybrid electrode showed significantly improved electrochemical performance. The as-fabricated hybrid electrode exhibited a high specific capacitance of 2318 F g^-1 at 1 A g^-1, with a superior cyclic stability. Additionally, an asymmetric supercapacitor (NCLP@NiMn-LDH//AC) was assembled with a voltage window of 1.5 V. The ASC device delivered a maximum energy density of 42.2 W h kg^-1 at a power density of 750 W kg^-1.