Heterogeneous oxidation of different atomic clusters in amorphous SiBCN ceramic associated with phase separation

Zi bo Niu; Daxin Li; Dechang Jia; Zhihua Yang; Kunpeng Lin; Paolo Colombo; Ralf Riedel; Yu Zhou

doi:10.1016/j.corsci.2023.111723

Heterogeneous oxidation of different atomic clusters in amorphous SiBCN ceramic associated with phase separation

Zi bo Niu
, Daxin Li^*
, Dechang Jia
, Zhihua Yang
, Kunpeng Lin
, Paolo Colombo
, Ralf Riedel
, Yu Zhou

^*Corresponding author for this work

Harbin Institute of Technology
Ministry of Industry and Information Technology
University of Padua
Pennsylvania State University
Technische Universität Darmstadt
Harbin Institute of Technology (Shenzhen)

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

In this study, the microstructure of amorphous SiBCN ceramic derived from polyborosilazane and the crystalline SiBCN ceramic heat treated at 1600 ℃ was investigated and their oxidation behavior and kinetics involving different atomic clusters or phases during the non-isothermal oxidation process up to 1500 ℃ were analyzed to obtain their different micro mechanisms. Due to higher oxidation activity, the atomic clusters in amorphous structure can be oxidized at lower temperatures and exhibit lower activation energy than the crystal phases in crystalline structure, but have much higher oxidation resistance due to the phase separation-coupled heterogeneous oxidation of different atomic clusters.

Original language	English
Article number	111723
Journal	Corrosion Science
Volume	227
DOIs	https://doi.org/10.1016/j.corsci.2023.111723
State	Published - Feb 2024

Keywords

Amorphous structure
Crystallization
Oxidation kinetics
SiBCN ceramic

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10.1016/j.corsci.2023.111723

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title = "Heterogeneous oxidation of different atomic clusters in amorphous SiBCN ceramic associated with phase separation",

abstract = "In this study, the microstructure of amorphous SiBCN ceramic derived from polyborosilazane and the crystalline SiBCN ceramic heat treated at 1600 ℃ was investigated and their oxidation behavior and kinetics involving different atomic clusters or phases during the non-isothermal oxidation process up to 1500 ℃ were analyzed to obtain their different micro mechanisms. Due to higher oxidation activity, the atomic clusters in amorphous structure can be oxidized at lower temperatures and exhibit lower activation energy than the crystal phases in crystalline structure, but have much higher oxidation resistance due to the phase separation-coupled heterogeneous oxidation of different atomic clusters.",

keywords = "Amorphous structure, Crystallization, Oxidation kinetics, SiBCN ceramic",

author = "Niu, \{Zi bo\} and Daxin Li and Dechang Jia and Zhihua Yang and Kunpeng Lin and Paolo Colombo and Ralf Riedel and Yu Zhou",

note = "Publisher Copyright: {\textcopyright} 2023 Elsevier Ltd",

year = "2024",

month = feb,

doi = "10.1016/j.corsci.2023.111723",

language = "英语",

volume = "227",

journal = "Corrosion Science",

issn = "0010-938X",

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TY - JOUR

T1 - Heterogeneous oxidation of different atomic clusters in amorphous SiBCN ceramic associated with phase separation

AU - Niu, Zi bo

AU - Li, Daxin

AU - Jia, Dechang

AU - Yang, Zhihua

AU - Lin, Kunpeng

AU - Colombo, Paolo

AU - Riedel, Ralf

AU - Zhou, Yu

PY - 2024/2

Y1 - 2024/2

N2 - In this study, the microstructure of amorphous SiBCN ceramic derived from polyborosilazane and the crystalline SiBCN ceramic heat treated at 1600 ℃ was investigated and their oxidation behavior and kinetics involving different atomic clusters or phases during the non-isothermal oxidation process up to 1500 ℃ were analyzed to obtain their different micro mechanisms. Due to higher oxidation activity, the atomic clusters in amorphous structure can be oxidized at lower temperatures and exhibit lower activation energy than the crystal phases in crystalline structure, but have much higher oxidation resistance due to the phase separation-coupled heterogeneous oxidation of different atomic clusters.

AB - In this study, the microstructure of amorphous SiBCN ceramic derived from polyborosilazane and the crystalline SiBCN ceramic heat treated at 1600 ℃ was investigated and their oxidation behavior and kinetics involving different atomic clusters or phases during the non-isothermal oxidation process up to 1500 ℃ were analyzed to obtain their different micro mechanisms. Due to higher oxidation activity, the atomic clusters in amorphous structure can be oxidized at lower temperatures and exhibit lower activation energy than the crystal phases in crystalline structure, but have much higher oxidation resistance due to the phase separation-coupled heterogeneous oxidation of different atomic clusters.

KW - Amorphous structure

KW - Crystallization

KW - Oxidation kinetics

KW - SiBCN ceramic

UR - https://www.scopus.com/pages/publications/85178594965

U2 - 10.1016/j.corsci.2023.111723

DO - 10.1016/j.corsci.2023.111723

M3 - 文章

AN - SCOPUS:85178594965

SN - 0010-938X

VL - 227

JO - Corrosion Science

JF - Corrosion Science

M1 - 111723

ER -

Heterogeneous oxidation of different atomic clusters in amorphous SiBCN ceramic associated with phase separation

Abstract

Keywords

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