Halide Ion-Mediated Synthesis of L1 ₀ -FePt Nanoparticles with Tunable Magnetic Properties

L1 ₀ -FePt nanoparticles (NPs) have great potential in areas of advanced magnetic and catalytic applications. Here, we present a facile control route for synthesis of hard magnetic L1 ₀ -FePt NPs in which halide ions (Cl ^- , Br ^- , or I ^- ) were added to the synthetic process to promote the phase transformation. It is confirmed that the strong ionic binding force between halide ions and Fe ³⁺ or Pt ²⁺ ions could facilitate the formation of L1 ₀ -FePt phase due to favoring growth of FePt NPs in a more thermodynamically stable way, which enables the formation of an ordered structure. L1 ₀ -FePt NPs with the highest coercivity of 8.64 kOe and saturation magnetization of 64.21 emu/g at room temperature can be directly obtained by controlling the amount of the halide ions. In comparison with conventional solution phase reduction methods, the halide ion-assisted method shows enhanced capability to tune the growth of hard magnetic bimetallic NPs, particularly Pt-based bimetallic NPs.