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Growth of YbVO 4 crystals evolved from hot corrosion reactions of Yb 2 Zr 2 O 7 against V 2 O 5 and Na 2 SO 4 + V 2 O 5

  • Harbin Institute of Technology

Research output: Contribution to journalArticlepeer-review

Abstract

Hot corrosion behavior of Yb 2 Zr 2 O 7 ceramic against V 2 O 5 and Na 2 SO 4 + V 2 O 5 (molar ratio = 1:1) was investigated at temperatures of 900-1100 C for 2 h in air. YbVO 4 was identified due to chemical interactions of these two corrosive agents with Yb 2 Zr 2 O 7 ceramic. Although YbVO 4 formed in these two hot corrosion reactions has the same crystallographic structural characteristic, its morphologies exhibit significant difference. YbVO 4 evolved from hot corrosion of V 2 O 5 -coated Yb 2 Zr 2 O 7 is particle-shaped, while it is rod-like in the (Na 2 SO 4 + V 2 O 5 )-coated Yb 2 Zr 2 O 7 . A model describing the formation process of the hot corrosion products was presented and the growth mechanism of YbVO 4 crystal was proposed on the basis of the hot corrosion model.

Original languageEnglish
Pages (from-to)653-659
Number of pages7
JournalApplied Surface Science
Volume276
DOIs
StatePublished - 1 Jul 2013
Externally publishedYes

Keywords

  • Hot corrosion
  • Microstructure

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