Growth of Vertical Graphene Sheets on Silicon Nanoparticles Well-Dispersed on Graphite Particles for High-Performance Lithium-Ion Battery Anode

With rapidly increasing demand for high energy density, silicon (Si) is greatly expected to play an important role as the anode material of lithium-ion batteries (LIBs) due to its high specific capacity. However, large volume expansion for silicon during the charging process is still a serious problem influencing its cycling stability. Here, a Si/C composite of vertical graphene sheets/silicon/carbon/graphite (VGSs@Si/C/G) is reported to address the electrochemical stability issues of Si/graphite anodes, which is prepared by adhering Si nanoparticles on graphite particles with chitosan and then in situ growing VGSs by thermal chemical vapor deposition. As a promising anode material, due to the buffering effect of VGSs and tight bonding between Si and graphite particles, the composite delivers a high reversible capacity of 782.2 mAh g⁻¹ after 1000 cycles with an initial coulombic efficiency of 87.2%. Furthermore, the VGSs@Si/C/G shows a diffusion coefficient of two orders higher than that without growing the VGSs. The full battery using VGSs@Si/C/G anode and LiNi_0.8Co_0.1Mn_0.1O₂ cathode achieves a high gravimetric energy density of 343.6 Wh kg⁻¹, a high capacity retention of 91.5% after 500 cycles and an excellent average CE of 99.9%.