Green and time-saving synthesis of MIL-100(Cr) and its catalytic performance

Ying Mao; Hui Qi; Gan Ye; Le Han; Wei Zhou; Wei Xu; Yinyong Sun

doi:10.1016/j.micromeso.2018.07.026

Green and time-saving synthesis of MIL-100(Cr) and its catalytic performance

Ying Mao
, Hui Qi
, Gan Ye
, Le Han
, Wei Zhou
, Wei Xu
, Yinyong Sun^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering, Harbin Institute of Technology
Jilin University
Heilongjiang University

Research output: Contribution to journal › Article › peer-review

55 Scopus citations

Abstract

MIL-100(Cr) is an important member of metal-organic frameworks due to its large surface area, unique pore structure, good stability and unsaturated metal sites. Generally, this material was synthesized with the addition of HF and solvent for a long crystallization time (96 h). In this work, we report that MIL-100(Cr) can be synthesized under HF- and solvent-free conditions in a short crystallization time (15 h). The obtained MIL-100(Cr) possessed high surface area and rich porosity. Additionally, such material exhibited enhanced catalytic performance in the oxidation reaction of benzyl alcohol, demonstrating that it has potential applications in catalysis.

Original language	English
Pages (from-to)	70-75
Number of pages	6
Journal	Microporous and Mesoporous Materials
Volume	274
DOIs	https://doi.org/10.1016/j.micromeso.2018.07.026
State	Published - 15 Jan 2019
Externally published	Yes

Keywords

Benzyl alcohol
Green synthesis
MIL-100(Cr)
Oxidation
Solvent-free

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10.1016/j.micromeso.2018.07.026

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title = "Green and time-saving synthesis of MIL-100(Cr) and its catalytic performance",

abstract = "MIL-100(Cr) is an important member of metal-organic frameworks due to its large surface area, unique pore structure, good stability and unsaturated metal sites. Generally, this material was synthesized with the addition of HF and solvent for a long crystallization time (96 h). In this work, we report that MIL-100(Cr) can be synthesized under HF- and solvent-free conditions in a short crystallization time (15 h). The obtained MIL-100(Cr) possessed high surface area and rich porosity. Additionally, such material exhibited enhanced catalytic performance in the oxidation reaction of benzyl alcohol, demonstrating that it has potential applications in catalysis.",

keywords = "Benzyl alcohol, Green synthesis, MIL-100(Cr), Oxidation, Solvent-free",

author = "Ying Mao and Hui Qi and Gan Ye and Le Han and Wei Zhou and Wei Xu and Yinyong Sun",

note = "Publisher Copyright: {\textcopyright} 2018 Elsevier Inc.",

year = "2019",

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day = "15",

doi = "10.1016/j.micromeso.2018.07.026",

language = "英语",

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pages = "70--75",

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TY - JOUR

T1 - Green and time-saving synthesis of MIL-100(Cr) and its catalytic performance

AU - Mao, Ying

AU - Qi, Hui

AU - Ye, Gan

AU - Han, Le

AU - Zhou, Wei

AU - Xu, Wei

AU - Sun, Yinyong

PY - 2019/1/15

Y1 - 2019/1/15

N2 - MIL-100(Cr) is an important member of metal-organic frameworks due to its large surface area, unique pore structure, good stability and unsaturated metal sites. Generally, this material was synthesized with the addition of HF and solvent for a long crystallization time (96 h). In this work, we report that MIL-100(Cr) can be synthesized under HF- and solvent-free conditions in a short crystallization time (15 h). The obtained MIL-100(Cr) possessed high surface area and rich porosity. Additionally, such material exhibited enhanced catalytic performance in the oxidation reaction of benzyl alcohol, demonstrating that it has potential applications in catalysis.

AB - MIL-100(Cr) is an important member of metal-organic frameworks due to its large surface area, unique pore structure, good stability and unsaturated metal sites. Generally, this material was synthesized with the addition of HF and solvent for a long crystallization time (96 h). In this work, we report that MIL-100(Cr) can be synthesized under HF- and solvent-free conditions in a short crystallization time (15 h). The obtained MIL-100(Cr) possessed high surface area and rich porosity. Additionally, such material exhibited enhanced catalytic performance in the oxidation reaction of benzyl alcohol, demonstrating that it has potential applications in catalysis.

KW - Benzyl alcohol

KW - Green synthesis

KW - MIL-100(Cr)

KW - Oxidation

KW - Solvent-free

UR - https://www.scopus.com/pages/publications/85050557058

U2 - 10.1016/j.micromeso.2018.07.026

DO - 10.1016/j.micromeso.2018.07.026

M3 - 文章

AN - SCOPUS:85050557058

SN - 1387-1811

VL - 274

SP - 70

EP - 75

JO - Microporous and Mesoporous Materials

JF - Microporous and Mesoporous Materials

ER -

Green and time-saving synthesis of MIL-100(Cr) and its catalytic performance

Abstract

Keywords

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