Fouling and chemically enhanced backwashing performance of low-pressure membranes during the treatment of shale gas produced water

The treatment of shale gas produced water (SGPW) for beneficial reuse is currently the most dominant and economical option. Membrane filtration is one preferred method to deal with SGPW, but membrane fouling is an unavoidable problem. In this study, two types of ultrafiltration (UF) membranes and one type of microfiltration (MF) membrane were investigated to treat SGPW from Sichuan basin. Results showed that increased total dissolved solid (31–40 g/L) and UV₂₅₄ (10–42.9 m⁻¹) were observed for the same shale gas plays, and the primary fluorescent organic substances were humic acid-like components. Compared to UF membranes with the flux decline by 2% to 60%, MF membranes with larger pore size were more likely to be fouled with the flux decline by 43% to 95%. Cake layer filtration was verified to be the primary membrane fouling mechanism. Statistical analysis showed that UV₂₅₄ played the most significant role in membrane fouling which had the highest correlation (0.76 to 0.93). Compared to permeate backwashing (13%), deionized water backwashing and chemically enhanced backwashing (CEB) using NaClO, H₂O₂ and citric acid improved the cleaning efficiencies (31%–95%). CEB using NaOH prepared by deionized water aggravated membrane fouling, while excellent cleaning efficiencies (39%–79%) were observed for CEB using NaOH prepared by permeate. The difference in cleaning behaviors for fouled membranes by SGPW was verified by morphology observation and element composition analysis.