Formation of monodisperse poly(methyl methacrylate) particles by radiation-induced dispersion polymerization. II. Particle size and size distribution

Qiang Ye; Zhicheng Zhang; Xuewu Ge; Yonghong Ni; Mozhen Wang

doi:10.1007/s00396-002-0652-9

Formation of monodisperse poly(methyl methacrylate) particles by radiation-induced dispersion polymerization. II. Particle size and size distribution

Qiang Ye^*
, Zhicheng Zhang
, Xuewu Ge
, Yonghong Ni
, Mozhen Wang

^*Corresponding author for this work

University of Science and Technology of China

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

Micron-sized poly(methyl methacrylate) particles were produced directly by radiation-induced dispersion polymerization in aqueous alcohol media using poly(N-vinylpyrrolidone) as a steric stabilizer at room temperature(10-35 °C). This method takes advantages of the specialities of radiation induction, and highly uniform polymer microspheres were obtained with high conversion. The gel effect was found from the polymerization kinetics curves. The number of nuclei produced in the early stage of the polymerization was found to be constant during the remainder of the polymerization. The effects of various polymerization parameters, such as irradiation dose rate, monomer concentration, stabilizer content, medium polarity, and polymerization temperature, on the particle size and the size distribution were investigated systematically.

Original language	English
Pages (from-to)	1091-1096
Number of pages	6
Journal	Colloid and Polymer Science
Volume	280
Issue number	12
DOIs	https://doi.org/10.1007/s00396-002-0652-9
State	Published - 2002
Externally published	Yes

Keywords

Monodisperse particles
Particle size and its distribution
Poly(methyl methacrylate)
Radiation-induced dispersion polymerization

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10.1007/s00396-002-0652-9

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title = "Formation of monodisperse poly(methyl methacrylate) particles by radiation-induced dispersion polymerization. II. Particle size and size distribution",

abstract = "Micron-sized poly(methyl methacrylate) particles were produced directly by radiation-induced dispersion polymerization in aqueous alcohol media using poly(N-vinylpyrrolidone) as a steric stabilizer at room temperature(10-35 °C). This method takes advantages of the specialities of radiation induction, and highly uniform polymer microspheres were obtained with high conversion. The gel effect was found from the polymerization kinetics curves. The number of nuclei produced in the early stage of the polymerization was found to be constant during the remainder of the polymerization. The effects of various polymerization parameters, such as irradiation dose rate, monomer concentration, stabilizer content, medium polarity, and polymerization temperature, on the particle size and the size distribution were investigated systematically.",

keywords = "Monodisperse particles, Particle size and its distribution, Poly(methyl methacrylate), Radiation-induced dispersion polymerization",

author = "Qiang Ye and Zhicheng Zhang and Xuewu Ge and Yonghong Ni and Mozhen Wang",

year = "2002",

doi = "10.1007/s00396-002-0652-9",

language = "英语",

volume = "280",

pages = "1091--1096",

journal = "Colloid and Polymer Science",

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number = "12",

}

TY - JOUR

T1 - Formation of monodisperse poly(methyl methacrylate) particles by radiation-induced dispersion polymerization. II. Particle size and size distribution

AU - Ye, Qiang

AU - Zhang, Zhicheng

AU - Ge, Xuewu

AU - Ni, Yonghong

AU - Wang, Mozhen

PY - 2002

Y1 - 2002

N2 - Micron-sized poly(methyl methacrylate) particles were produced directly by radiation-induced dispersion polymerization in aqueous alcohol media using poly(N-vinylpyrrolidone) as a steric stabilizer at room temperature(10-35 °C). This method takes advantages of the specialities of radiation induction, and highly uniform polymer microspheres were obtained with high conversion. The gel effect was found from the polymerization kinetics curves. The number of nuclei produced in the early stage of the polymerization was found to be constant during the remainder of the polymerization. The effects of various polymerization parameters, such as irradiation dose rate, monomer concentration, stabilizer content, medium polarity, and polymerization temperature, on the particle size and the size distribution were investigated systematically.

AB - Micron-sized poly(methyl methacrylate) particles were produced directly by radiation-induced dispersion polymerization in aqueous alcohol media using poly(N-vinylpyrrolidone) as a steric stabilizer at room temperature(10-35 °C). This method takes advantages of the specialities of radiation induction, and highly uniform polymer microspheres were obtained with high conversion. The gel effect was found from the polymerization kinetics curves. The number of nuclei produced in the early stage of the polymerization was found to be constant during the remainder of the polymerization. The effects of various polymerization parameters, such as irradiation dose rate, monomer concentration, stabilizer content, medium polarity, and polymerization temperature, on the particle size and the size distribution were investigated systematically.

KW - Monodisperse particles

KW - Particle size and its distribution

KW - Poly(methyl methacrylate)

KW - Radiation-induced dispersion polymerization

UR - https://www.scopus.com/pages/publications/0036944578

U2 - 10.1007/s00396-002-0652-9

DO - 10.1007/s00396-002-0652-9

M3 - 文章

AN - SCOPUS:0036944578

SN - 0303-402X

VL - 280

SP - 1091

EP - 1096

JO - Colloid and Polymer Science

JF - Colloid and Polymer Science

IS - 12

ER -

Formation of monodisperse poly(methyl methacrylate) particles by radiation-induced dispersion polymerization. II. Particle size and size distribution

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Keywords

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