Facile synthesis of Sb-Sb2O5@P@C composite and study for the supercapacitor application

Zongsheng Cao; Zhengchun Yang; Cong Zhang; Liqiang Xie; Xinhao Zhao; Peng Pan; Yujie Yuan; Wen Qi; Jie He; Honghao Zhang; Tao Xue; Ping Zhang; Jun Wei; Kailiang Zhang; Jinshi Zhao

doi:10.1007/s10854-019-02776-x

Facile synthesis of Sb-Sb₂O₅@P@C composite and study for the supercapacitor application

Zongsheng Cao
, Zhengchun Yang
, Cong Zhang
, Liqiang Xie
, Xinhao Zhao
, Peng Pan
, Yujie Yuan
, Wen Qi
, Jie He^*
, Honghao Zhang
, Tao Xue
, Ping Zhang
, Jun Wei
, Kailiang Zhang
, Jinshi Zhao

^*Corresponding author for this work

Tianjin University of Technology
Beijing Institute of Collaborative Innovation
Tianjin University
Agency for Science, Technology and Research, Singapore

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

A Sb-Sb₂O₅@P@C composite was synthesized using a two-step high-energy mechanical milling (HEMM) method using metal antimony, red phosphorus, and carbon as raw materials. XPS, XRD, and Raman spectroscopy clearly showed that the Sb was partially oxidized to become Sb₂O₅ during the milling process and that some of the red phosphorus was converted to black phosphorus. A specific capacitance of 109.7 F g⁻¹ was achieved at a current density of 0.5 mA cm^-2 in the obtained Sb-Sb₂O₅@P@C composite, and the packaged supercapacitor prepared with the Sb-Sb₂O₅@P@C composite was found to maintain a capacitance retention of 77.3% after 5000 cycles at a current density of 2 A g⁻¹. This study therefore provides a possible direction for the selection of electrode materials the perform well for application in supercapacitors.

Original language	English
Pages (from-to)	2406-2415
Number of pages	10
Journal	Journal of Materials Science: Materials in Electronics
Volume	31
Issue number	3
DOIs	https://doi.org/10.1007/s10854-019-02776-x
State	Published - 1 Feb 2020
Externally published	Yes

Keywords

Black phosphorus
Capacitance retention
HEMM
Sb-SbO@P@C
Supercapacitor

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10.1007/s10854-019-02776-x

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@article{ef1c56dc94904343a4854d5cbf2b6c34,

title = "Facile synthesis of Sb-Sb2O5@P@C composite and study for the supercapacitor application",

abstract = "A Sb-Sb2O5@P@C composite was synthesized using a two-step high-energy mechanical milling (HEMM) method using metal antimony, red phosphorus, and carbon as raw materials. XPS, XRD, and Raman spectroscopy clearly showed that the Sb was partially oxidized to become Sb2O5 during the milling process and that some of the red phosphorus was converted to black phosphorus. A specific capacitance of 109.7 F g−1 was achieved at a current density of 0.5 mA cm-2 in the obtained Sb-Sb2O5@P@C composite, and the packaged supercapacitor prepared with the Sb-Sb2O5@P@C composite was found to maintain a capacitance retention of 77.3\% after 5000 cycles at a current density of 2 A g−1. This study therefore provides a possible direction for the selection of electrode materials the perform well for application in supercapacitors.",

keywords = "Black phosphorus, Capacitance retention, HEMM, Sb-SbO@P@C, Supercapacitor",

author = "Zongsheng Cao and Zhengchun Yang and Cong Zhang and Liqiang Xie and Xinhao Zhao and Peng Pan and Yujie Yuan and Wen Qi and Jie He and Honghao Zhang and Tao Xue and Ping Zhang and Jun Wei and Kailiang Zhang and Jinshi Zhao",

note = "Publisher Copyright: {\textcopyright} 2020, Springer Science+Business Media, LLC, part of Springer Nature.",

year = "2020",

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doi = "10.1007/s10854-019-02776-x",

language = "英语",

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TY - JOUR

T1 - Facile synthesis of Sb-Sb2O5@P@C composite and study for the supercapacitor application

AU - Cao, Zongsheng

AU - Yang, Zhengchun

AU - Zhang, Cong

AU - Xie, Liqiang

AU - Zhao, Xinhao

AU - Pan, Peng

AU - Yuan, Yujie

AU - Qi, Wen

AU - He, Jie

AU - Zhang, Honghao

AU - Xue, Tao

AU - Zhang, Ping

AU - Wei, Jun

AU - Zhang, Kailiang

AU - Zhao, Jinshi

PY - 2020/2/1

Y1 - 2020/2/1

N2 - A Sb-Sb2O5@P@C composite was synthesized using a two-step high-energy mechanical milling (HEMM) method using metal antimony, red phosphorus, and carbon as raw materials. XPS, XRD, and Raman spectroscopy clearly showed that the Sb was partially oxidized to become Sb2O5 during the milling process and that some of the red phosphorus was converted to black phosphorus. A specific capacitance of 109.7 F g−1 was achieved at a current density of 0.5 mA cm-2 in the obtained Sb-Sb2O5@P@C composite, and the packaged supercapacitor prepared with the Sb-Sb2O5@P@C composite was found to maintain a capacitance retention of 77.3% after 5000 cycles at a current density of 2 A g−1. This study therefore provides a possible direction for the selection of electrode materials the perform well for application in supercapacitors.

AB - A Sb-Sb2O5@P@C composite was synthesized using a two-step high-energy mechanical milling (HEMM) method using metal antimony, red phosphorus, and carbon as raw materials. XPS, XRD, and Raman spectroscopy clearly showed that the Sb was partially oxidized to become Sb2O5 during the milling process and that some of the red phosphorus was converted to black phosphorus. A specific capacitance of 109.7 F g−1 was achieved at a current density of 0.5 mA cm-2 in the obtained Sb-Sb2O5@P@C composite, and the packaged supercapacitor prepared with the Sb-Sb2O5@P@C composite was found to maintain a capacitance retention of 77.3% after 5000 cycles at a current density of 2 A g−1. This study therefore provides a possible direction for the selection of electrode materials the perform well for application in supercapacitors.

KW - Black phosphorus

KW - Capacitance retention

KW - HEMM

KW - Sb-SbO@P@C

KW - Supercapacitor

UR - https://www.scopus.com/pages/publications/85077520856

U2 - 10.1007/s10854-019-02776-x

DO - 10.1007/s10854-019-02776-x

M3 - 文章

AN - SCOPUS:85077520856

SN - 0957-4522

VL - 31

SP - 2406

EP - 2415

JO - Journal of Materials Science: Materials in Electronics

JF - Journal of Materials Science: Materials in Electronics

IS - 3

ER -

Facile synthesis of Sb-Sb₂O₅@P@C composite and study for the supercapacitor application

Abstract

Keywords

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