Facile synthesis of polyaniline-polypyrrole nanofibers for application in chemical deposition of metal nanoparticles

Ping Xu; Xijiang Han; Chao Wang; Bin Zhang; Xiaohong Wang; Hsing Lin Wang

doi:10.1002/marc.200800173

Facile synthesis of polyaniline-polypyrrole nanofibers for application in chemical deposition of metal nanoparticles

Ping Xu
, Xijiang Han^*
, Chao Wang
, Bin Zhang
, Xiaohong Wang
, Hsing Lin Wang

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Harbin Institute of Technology
Beijing Institute of Aeronautical Materials
Los Alamos National Laboratory

Research output: Contribution to journal › Article › peer-review

60 Scopus citations

Abstract

Polyaniline-polypyrrole (PANI-PPy) nanofibers with high aspect ratios have been synthesized by a one-step, surfactant-assisted chemical oxidative polymerization from mixtures of aniline (An) and pyrrole (Py) monomers. PANI-PPy nanofibers synthesized with an excess of either PANI or PPy show similar spectral (UV-vis and FT-IR) characteristics as the individual homopolymers, whereas nanofibers from an equimolar mixture of An and Py display unique spectral characteristics. PANI-PPy nanofibers undergo a spontaneous redox reaction with metal ions to produce metal nanoparticles with various morphologies and/or sizes. These findings may open new opportunities for synthesizing functional polymer nanofibers and metal nanoparticles with controllable sizes and/or morphologies.

Original language	English
Pages (from-to)	1392-1397
Number of pages	6
Journal	Macromolecular Rapid Communications
Volume	29
Issue number	16
DOIs	https://doi.org/10.1002/marc.200800173
State	Published - 18 Aug 2008

Keywords

Fibers
Nanoparticles
Polyanilines
Polypyrroles
Synthesis

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10.1002/marc.200800173

Cite this

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title = "Facile synthesis of polyaniline-polypyrrole nanofibers for application in chemical deposition of metal nanoparticles",

abstract = "Polyaniline-polypyrrole (PANI-PPy) nanofibers with high aspect ratios have been synthesized by a one-step, surfactant-assisted chemical oxidative polymerization from mixtures of aniline (An) and pyrrole (Py) monomers. PANI-PPy nanofibers synthesized with an excess of either PANI or PPy show similar spectral (UV-vis and FT-IR) characteristics as the individual homopolymers, whereas nanofibers from an equimolar mixture of An and Py display unique spectral characteristics. PANI-PPy nanofibers undergo a spontaneous redox reaction with metal ions to produce metal nanoparticles with various morphologies and/or sizes. These findings may open new opportunities for synthesizing functional polymer nanofibers and metal nanoparticles with controllable sizes and/or morphologies.",

keywords = "Fibers, Nanoparticles, Polyanilines, Polypyrroles, Synthesis",

author = "Ping Xu and Xijiang Han and Chao Wang and Bin Zhang and Xiaohong Wang and Wang, \{Hsing Lin\}",

year = "2008",

month = aug,

day = "18",

doi = "10.1002/marc.200800173",

language = "英语",

volume = "29",

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journal = "Macromolecular Rapid Communications",

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TY - JOUR

T1 - Facile synthesis of polyaniline-polypyrrole nanofibers for application in chemical deposition of metal nanoparticles

AU - Xu, Ping

AU - Han, Xijiang

AU - Wang, Chao

AU - Zhang, Bin

AU - Wang, Xiaohong

AU - Wang, Hsing Lin

PY - 2008/8/18

Y1 - 2008/8/18

N2 - Polyaniline-polypyrrole (PANI-PPy) nanofibers with high aspect ratios have been synthesized by a one-step, surfactant-assisted chemical oxidative polymerization from mixtures of aniline (An) and pyrrole (Py) monomers. PANI-PPy nanofibers synthesized with an excess of either PANI or PPy show similar spectral (UV-vis and FT-IR) characteristics as the individual homopolymers, whereas nanofibers from an equimolar mixture of An and Py display unique spectral characteristics. PANI-PPy nanofibers undergo a spontaneous redox reaction with metal ions to produce metal nanoparticles with various morphologies and/or sizes. These findings may open new opportunities for synthesizing functional polymer nanofibers and metal nanoparticles with controllable sizes and/or morphologies.

AB - Polyaniline-polypyrrole (PANI-PPy) nanofibers with high aspect ratios have been synthesized by a one-step, surfactant-assisted chemical oxidative polymerization from mixtures of aniline (An) and pyrrole (Py) monomers. PANI-PPy nanofibers synthesized with an excess of either PANI or PPy show similar spectral (UV-vis and FT-IR) characteristics as the individual homopolymers, whereas nanofibers from an equimolar mixture of An and Py display unique spectral characteristics. PANI-PPy nanofibers undergo a spontaneous redox reaction with metal ions to produce metal nanoparticles with various morphologies and/or sizes. These findings may open new opportunities for synthesizing functional polymer nanofibers and metal nanoparticles with controllable sizes and/or morphologies.

KW - Fibers

KW - Nanoparticles

KW - Polyanilines

KW - Polypyrroles

KW - Synthesis

UR - https://www.scopus.com/pages/publications/54949122982

U2 - 10.1002/marc.200800173

DO - 10.1002/marc.200800173

M3 - 文章

AN - SCOPUS:54949122982

SN - 1022-1336

VL - 29

SP - 1392

EP - 1397

JO - Macromolecular Rapid Communications

JF - Macromolecular Rapid Communications

IS - 16

ER -

Facile synthesis of polyaniline-polypyrrole nanofibers for application in chemical deposition of metal nanoparticles

Abstract

Keywords

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