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Facile fabrication of TiO 2 @TiO 2 transparent free-standing film for photocatalysis

  • Shanmei Zhang
  • , Yue Hu
  • , Luyang Hu*
  • , Yumin Zhang
  • , Yufeng Zhou
  • , Benxia Li
  • *Corresponding author for this work
  • Anhui University of Science and Technology
  • Harbin Institute of Technology
  • Zhejiang Sci-Tech University

Research output: Contribution to journalArticlepeer-review

Abstract

A transparent titanium dioxide (TiO 2 )@TiO 2 film with free-standing structure was synthesised by employing a cellulose paper as the template. By one-step hydrothermal method and subsequent thermal annealing, the fibre of cellulose paper was changed into porous TiO 2 core layer. The flower-like micro/nanostructure TiO 2 particle layer was intimately distributed on the porous TiO 2 core layer. The average diameter of the TiO 2 @TiO 2 fibre for the film was 11 µm. The size of spherical granular TiO 2 on the fibre surface was around 330 ± 130 nm. It was noted that the microtopography of fibre surface could be adjusted by tuning the hydrothermal temperature. The scanning electron microscopy and N 2 adsorption-desorption measurement results indicated that the prepared film possessed a large mass of mesopores and macropores. On the basis of the special microstructure, the TiO 2 @TiO 2 film exhibited high photocatalytic activity for methylene blue under ultraviolet irradiation. This work might provide a new insight for preparation of transparent photocatalytic film toward water purification.

Original languageEnglish
Pages (from-to)42-44
Number of pages3
JournalMicro and Nano Letters
Volume14
Issue number1
DOIs
StatePublished - 2019

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