Fabrication of Au-polymer hybrid colloids via a pH-modulated in situ reduction process for improved catalytic activity

Here, we reported a novel strategy for the controllable synthesis of Au nanoparticles within functional microgels. By simply mixing Au(Cl)₄^- ions with a microgel dispersion at room temperature for several hours, Au(III) ions were reduced into Au(0) nanoparticles on the surface of the microgels. Without the use of any additional reductant, the reduction of the Au(III) ions was realized and controlled by tuning the volume of the base solution as a result of the unique reductive 3-carbonyl-N-vinylcaprolactam structure inside the microgels. Moreover, the hybrid microgels showed efficient catalytic activities for the model reduction reaction of 4-nitrophenol (Nip). These results revealed that the synthesis strategy of fabricating Au-polymer hybrids possesses great potential in the field of wastewater treatment.