Fabrication Method, Ferromagnetic Resonance Spectroscopy and Spintronics Devices Based on the Organic-Based Ferrimagnet Vanadium Tetracyanoethylene

Organic-based magnetic materials have been used for spintronic device applications as electrodes of spin aligned carriers and spin-pumping substrates. Their advantages over more traditional inorganic magnets include reduced magnetic damping and lower fabrication costs. Vanadium tetracyanoethylene, V[TCNE]_x (x ≈ 2), is an organic-based ferrimagnet with an above room-temperature magnetic order temperature (T_c ≈ 400 K). V[TCNE]_x has deposition flexibility and can be grown on a variety of substrates via low-temperature chemical vapor deposition (CVD). A systematic study of V[TCNE]_x thin-film CVD parameters to achieve optimal film quality, reproducibility, and excellent magnetic properties is reported. This is assessed by broadband ferromagnetic resonance (FMR) that shows most narrow linewidth of ≈1.5 Gauss and an extremely low Gilbert damping coefficient. The neat V[TCNE]_x films are shown to be efficient spin injectors via spin pumping into an adjacent platinum layer. Also, under an optimized FMR linewidth, the V[TCNE]_x films exhibit Fano-type resonance with a continuum broadband absorption in the microwave range, which can be readily tuned by the microwave frequency.