Excited-state nonlinear optical properties of metal cluster W2Ag4S8(dppf)2

Bin Dong; Jifeng Zu; Yachen Gao; Yinglin Song; Mingkai Lei

Excited-state nonlinear optical properties of metal cluster W₂Ag₄S₈(dppf)₂

Bin Dong
, Jifeng Zu
, Yachen Gao
, Yinglin Song
, Mingkai Lei^*

^*Corresponding author for this work

School of Physics

Dalian University of Technology
Chinese Academy of Sciences
Harbin Institute of Technology

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The nonlinear optical effect of metal cluster compound W₂Ag₄S₈(dppf)₂ was investigated using frequency-doubled, Q-switched Nd-YAG pulse laser system with wavelength of 532 nm and pulse width of 8 ns. The cluster W₂Ag₄S₈(dppf)₂ possessed reverse saturation absorption and self-focusing refraction. The nonlinear absorption and nonlinear refraction of the cluster W₂Ag₄S₈(dppf)₂ were explained with excited-state theory. The theoretical results are in agreement with the experimental data. The ratio of cross-section of the absorption of the excited-state to that of the ground-state K_a and the ratio of refraction volumes of the excited-state to that of the ground-state K_r were gained based on their simulation of numerical value. The effective third-order susceptibility x⁽³⁾ determined for the cluster. The experiment results show that the cluster W₂Ag₄S₈(dppf)₂ has good optical limiting character for nanometer pulse.

Original language	English
Pages (from-to)	668-672
Number of pages	5
Journal	Cailiao Yanjiu Xuebao/Chinese Journal of Materials Research
Volume	18
Issue number	6
State	Published - Dec 2004

Keywords

Excited-state absorption
Excited-state refraction
Inorganic non-metallic materials
Materials
Metal cluster compound
Nonlinear optics
Z-scan

Cite this

@article{876c1d0e0dca4483ac4a2be1d80256b0,

title = "Excited-state nonlinear optical properties of metal cluster W2Ag4S8(dppf)2",

abstract = "The nonlinear optical effect of metal cluster compound W2Ag4S8(dppf)2 was investigated using frequency-doubled, Q-switched Nd-YAG pulse laser system with wavelength of 532 nm and pulse width of 8 ns. The cluster W2Ag4S8(dppf)2 possessed reverse saturation absorption and self-focusing refraction. The nonlinear absorption and nonlinear refraction of the cluster W2Ag4S8(dppf)2 were explained with excited-state theory. The theoretical results are in agreement with the experimental data. The ratio of cross-section of the absorption of the excited-state to that of the ground-state Ka and the ratio of refraction volumes of the excited-state to that of the ground-state Kr were gained based on their simulation of numerical value. The effective third-order susceptibility x(3) determined for the cluster. The experiment results show that the cluster W2Ag4S8(dppf)2 has good optical limiting character for nanometer pulse.",

keywords = "Excited-state absorption, Excited-state refraction, Inorganic non-metallic materials, Materials, Metal cluster compound, Nonlinear optics, Z-scan",

author = "Bin Dong and Jifeng Zu and Yachen Gao and Yinglin Song and Mingkai Lei",

year = "2004",

month = dec,

language = "英语",

volume = "18",

pages = "668--672",

journal = "Cailiao Yanjiu Xuebao/Chinese Journal of Materials Research",

issn = "1005-3093",

publisher = "Chinese Journal of Materials Research",

number = "6",

}

TY - JOUR

T1 - Excited-state nonlinear optical properties of metal cluster W2Ag4S8(dppf)2

AU - Dong, Bin

AU - Zu, Jifeng

AU - Gao, Yachen

AU - Song, Yinglin

AU - Lei, Mingkai

PY - 2004/12

Y1 - 2004/12

N2 - The nonlinear optical effect of metal cluster compound W2Ag4S8(dppf)2 was investigated using frequency-doubled, Q-switched Nd-YAG pulse laser system with wavelength of 532 nm and pulse width of 8 ns. The cluster W2Ag4S8(dppf)2 possessed reverse saturation absorption and self-focusing refraction. The nonlinear absorption and nonlinear refraction of the cluster W2Ag4S8(dppf)2 were explained with excited-state theory. The theoretical results are in agreement with the experimental data. The ratio of cross-section of the absorption of the excited-state to that of the ground-state Ka and the ratio of refraction volumes of the excited-state to that of the ground-state Kr were gained based on their simulation of numerical value. The effective third-order susceptibility x(3) determined for the cluster. The experiment results show that the cluster W2Ag4S8(dppf)2 has good optical limiting character for nanometer pulse.

AB - The nonlinear optical effect of metal cluster compound W2Ag4S8(dppf)2 was investigated using frequency-doubled, Q-switched Nd-YAG pulse laser system with wavelength of 532 nm and pulse width of 8 ns. The cluster W2Ag4S8(dppf)2 possessed reverse saturation absorption and self-focusing refraction. The nonlinear absorption and nonlinear refraction of the cluster W2Ag4S8(dppf)2 were explained with excited-state theory. The theoretical results are in agreement with the experimental data. The ratio of cross-section of the absorption of the excited-state to that of the ground-state Ka and the ratio of refraction volumes of the excited-state to that of the ground-state Kr were gained based on their simulation of numerical value. The effective third-order susceptibility x(3) determined for the cluster. The experiment results show that the cluster W2Ag4S8(dppf)2 has good optical limiting character for nanometer pulse.

KW - Excited-state absorption

KW - Excited-state refraction

KW - Inorganic non-metallic materials

KW - Materials

KW - Metal cluster compound

KW - Nonlinear optics

KW - Z-scan

UR - https://www.scopus.com/pages/publications/14344258007

M3 - 文章

AN - SCOPUS:14344258007

SN - 1005-3093

VL - 18

SP - 668

EP - 672

JO - Cailiao Yanjiu Xuebao/Chinese Journal of Materials Research

JF - Cailiao Yanjiu Xuebao/Chinese Journal of Materials Research

IS - 6

ER -

Excited-state nonlinear optical properties of metal cluster W₂Ag₄S₈(dppf)₂

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