Enhancement of Two-Photon Absorption in Boron-Dipyrromethene (BODIPY) Derivatives

Guanzheng Song; Zhongguo Li; Yanbing Han; Jidong Jia; Wenfa Zhou; Xueru Zhang; Yuxiao Wang; Yinglin Song

doi:10.3390/molecules27092849

Enhancement of Two-Photon Absorption in Boron-Dipyrromethene (BODIPY) Derivatives

Guanzheng Song
, Zhongguo Li
, Yanbing Han
, Jidong Jia
, Wenfa Zhou
, Xueru Zhang^*
, Yuxiao Wang
, Yinglin Song^*

^*Corresponding author for this work

School of Physics

Harbin Institute of Technology
Changshu Institute of Technology

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

The linear and nonlinear optical properties of two BODIPY derivatives, 1,7-Diphenyl-3,5-bis(9,9-dimethyl-9H-fluoren-2-yl)-boron-diuoride-azadipyrromethene (ZL-61) and 1,7-Diphenyl-3,5-bis(4-(1,2,2-triphenylvinyl)phenyl)-boron-diuoride-azadipyrromethene (ZL-22), were comprehensively investigated based on experimental and theoretical studies. It was found that both compounds show a strong two-photon absorption response in the near-infrared regime, and the two-photon-absorption cross-section values of ZL-61 and ZL-22 were determined to be 8321 GM and 1864 GM at 800 nm, respectively. The improvement of the two-photon absorption cross section in ZL-61 was attributed to the enhancement of the donor group, which was con-firmed by transient absorption measurements and DFT calculation. Our results indicate that these BODIPY derivatives are a promising candidate for optical limiting and two-photon imaging applications.

Original language	English
Article number	2849
Journal	Molecules
Volume	27
Issue number	9
DOIs	https://doi.org/10.3390/molecules27092849
State	Published - 1 May 2022

Keywords

azaBODIPYs
nonlinear optics
optical limiting
two-photon absorption

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10.3390/molecules27092849

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@article{12f3f1c96b3a4913a9a4b35212769cb3,

title = "Enhancement of Two-Photon Absorption in Boron-Dipyrromethene (BODIPY) Derivatives",

abstract = "The linear and nonlinear optical properties of two BODIPY derivatives, 1,7-Diphenyl-3,5-bis(9,9-dimethyl-9H-fluoren-2-yl)-boron-diuoride-azadipyrromethene (ZL-61) and 1,7-Diphenyl-3,5-bis(4-(1,2,2-triphenylvinyl)phenyl)-boron-diuoride-azadipyrromethene (ZL-22), were comprehensively investigated based on experimental and theoretical studies. It was found that both compounds show a strong two-photon absorption response in the near-infrared regime, and the two-photon-absorption cross-section values of ZL-61 and ZL-22 were determined to be 8321 GM and 1864 GM at 800 nm, respectively. The improvement of the two-photon absorption cross section in ZL-61 was attributed to the enhancement of the donor group, which was con-firmed by transient absorption measurements and DFT calculation. Our results indicate that these BODIPY derivatives are a promising candidate for optical limiting and two-photon imaging applications.",

keywords = "azaBODIPYs, nonlinear optics, optical limiting, two-photon absorption",

author = "Guanzheng Song and Zhongguo Li and Yanbing Han and Jidong Jia and Wenfa Zhou and Xueru Zhang and Yuxiao Wang and Yinglin Song",

note = "Publisher Copyright: {\textcopyright} 2022 by the authors. Licensee MDPI, Basel, Switzerland.",

year = "2022",

month = may,

day = "1",

doi = "10.3390/molecules27092849",

language = "英语",

volume = "27",

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T1 - Enhancement of Two-Photon Absorption in Boron-Dipyrromethene (BODIPY) Derivatives

AU - Song, Guanzheng

AU - Li, Zhongguo

AU - Han, Yanbing

AU - Jia, Jidong

AU - Zhou, Wenfa

AU - Zhang, Xueru

AU - Wang, Yuxiao

AU - Song, Yinglin

PY - 2022/5/1

Y1 - 2022/5/1

N2 - The linear and nonlinear optical properties of two BODIPY derivatives, 1,7-Diphenyl-3,5-bis(9,9-dimethyl-9H-fluoren-2-yl)-boron-diuoride-azadipyrromethene (ZL-61) and 1,7-Diphenyl-3,5-bis(4-(1,2,2-triphenylvinyl)phenyl)-boron-diuoride-azadipyrromethene (ZL-22), were comprehensively investigated based on experimental and theoretical studies. It was found that both compounds show a strong two-photon absorption response in the near-infrared regime, and the two-photon-absorption cross-section values of ZL-61 and ZL-22 were determined to be 8321 GM and 1864 GM at 800 nm, respectively. The improvement of the two-photon absorption cross section in ZL-61 was attributed to the enhancement of the donor group, which was con-firmed by transient absorption measurements and DFT calculation. Our results indicate that these BODIPY derivatives are a promising candidate for optical limiting and two-photon imaging applications.

AB - The linear and nonlinear optical properties of two BODIPY derivatives, 1,7-Diphenyl-3,5-bis(9,9-dimethyl-9H-fluoren-2-yl)-boron-diuoride-azadipyrromethene (ZL-61) and 1,7-Diphenyl-3,5-bis(4-(1,2,2-triphenylvinyl)phenyl)-boron-diuoride-azadipyrromethene (ZL-22), were comprehensively investigated based on experimental and theoretical studies. It was found that both compounds show a strong two-photon absorption response in the near-infrared regime, and the two-photon-absorption cross-section values of ZL-61 and ZL-22 were determined to be 8321 GM and 1864 GM at 800 nm, respectively. The improvement of the two-photon absorption cross section in ZL-61 was attributed to the enhancement of the donor group, which was con-firmed by transient absorption measurements and DFT calculation. Our results indicate that these BODIPY derivatives are a promising candidate for optical limiting and two-photon imaging applications.

KW - azaBODIPYs

KW - nonlinear optics

KW - optical limiting

KW - two-photon absorption

UR - https://www.scopus.com/pages/publications/85129845465

U2 - 10.3390/molecules27092849

DO - 10.3390/molecules27092849

M3 - 文章

C2 - 35566197

AN - SCOPUS:85129845465

SN - 1420-3049

VL - 27

JO - Molecules

JF - Molecules

IS - 9

M1 - 2849

ER -

Enhancement of Two-Photon Absorption in Boron-Dipyrromethene (BODIPY) Derivatives

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