Enhancement of oxygen sensing performance of metalloporphyrin film modified with nano Al2O3 powder

Honglin Zhang; Ke Zhang; Zhiguo Zhiguo; Jian Hao

doi:10.1016/j.heliyon.2023.e18300

Enhancement of oxygen sensing performance of metalloporphyrin film modified with nano Al₂O₃ powder

Honglin Zhang^*
, Ke Zhang
, Zhiguo Zhiguo
, Jian Hao

^*Corresponding author for this work

Guangzhou Huali College
School of Chemistry and Chemical Engineering, Harbin Institute of Technology
Harbin Institute of Technology
Ningxia University

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

In this work, the metalloporphyrin film of PtOEP/Poly (St-co-TFEMA) modified by nano Al₂O₃ powder was prepared, and the enhancement performance of oxygen sensing was studied in detail. It was verified that the modified film extended the residence time of oxygen through the characterization of SEM. The phosphorescence intensity changes with the content of Al₂O₃ and PtOEP were studied. The Stern-Volmer equations before and after modification of Al₂O₃ powder was compared. It was found that the linearity of the calibration curve was still high, but the oxygen sensitivity value of K_SV was significantly improved due to the increase of quenching probability between indicator and oxygen. Finally, the stability test shows that the Al₂O₃@PtOEP/Poly (St-co-TFEMA) oxygen sensing film presents a strong anti-photo-bleaching ability, and the response time is shortened.

Original language	English
Article number	e18300
Journal	Heliyon
Volume	9
Issue number	7
DOIs	https://doi.org/10.1016/j.heliyon.2023.e18300
State	Published - Jul 2023
Externally published	Yes

Keywords

AlO modification
Oxygen sensing
Stern-volmer equation

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10.1016/j.heliyon.2023.e18300

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title = "Enhancement of oxygen sensing performance of metalloporphyrin film modified with nano Al2O3 powder",

abstract = "In this work, the metalloporphyrin film of PtOEP/Poly (St-co-TFEMA) modified by nano Al2O3 powder was prepared, and the enhancement performance of oxygen sensing was studied in detail. It was verified that the modified film extended the residence time of oxygen through the characterization of SEM. The phosphorescence intensity changes with the content of Al2O3 and PtOEP were studied. The Stern-Volmer equations before and after modification of Al2O3 powder was compared. It was found that the linearity of the calibration curve was still high, but the oxygen sensitivity value of KSV was significantly improved due to the increase of quenching probability between indicator and oxygen. Finally, the stability test shows that the Al2O3@PtOEP/Poly (St-co-TFEMA) oxygen sensing film presents a strong anti-photo-bleaching ability, and the response time is shortened.",

keywords = "AlO modification, Oxygen sensing, Stern-volmer equation",

author = "Honglin Zhang and Ke Zhang and Zhiguo Zhiguo and Jian Hao",

note = "Publisher Copyright: {\textcopyright} 2023 The Author(s)",

year = "2023",

month = jul,

doi = "10.1016/j.heliyon.2023.e18300",

language = "英语",

volume = "9",

journal = "Heliyon",

issn = "2405-8440",

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}

TY - JOUR

T1 - Enhancement of oxygen sensing performance of metalloporphyrin film modified with nano Al2O3 powder

AU - Zhang, Honglin

AU - Zhang, Ke

AU - Zhiguo, Zhiguo

AU - Hao, Jian

PY - 2023/7

Y1 - 2023/7

N2 - In this work, the metalloporphyrin film of PtOEP/Poly (St-co-TFEMA) modified by nano Al2O3 powder was prepared, and the enhancement performance of oxygen sensing was studied in detail. It was verified that the modified film extended the residence time of oxygen through the characterization of SEM. The phosphorescence intensity changes with the content of Al2O3 and PtOEP were studied. The Stern-Volmer equations before and after modification of Al2O3 powder was compared. It was found that the linearity of the calibration curve was still high, but the oxygen sensitivity value of KSV was significantly improved due to the increase of quenching probability between indicator and oxygen. Finally, the stability test shows that the Al2O3@PtOEP/Poly (St-co-TFEMA) oxygen sensing film presents a strong anti-photo-bleaching ability, and the response time is shortened.

AB - In this work, the metalloporphyrin film of PtOEP/Poly (St-co-TFEMA) modified by nano Al2O3 powder was prepared, and the enhancement performance of oxygen sensing was studied in detail. It was verified that the modified film extended the residence time of oxygen through the characterization of SEM. The phosphorescence intensity changes with the content of Al2O3 and PtOEP were studied. The Stern-Volmer equations before and after modification of Al2O3 powder was compared. It was found that the linearity of the calibration curve was still high, but the oxygen sensitivity value of KSV was significantly improved due to the increase of quenching probability between indicator and oxygen. Finally, the stability test shows that the Al2O3@PtOEP/Poly (St-co-TFEMA) oxygen sensing film presents a strong anti-photo-bleaching ability, and the response time is shortened.

KW - AlO modification

KW - Oxygen sensing

KW - Stern-volmer equation

UR - https://www.scopus.com/pages/publications/85165103559

U2 - 10.1016/j.heliyon.2023.e18300

DO - 10.1016/j.heliyon.2023.e18300

M3 - 文章

AN - SCOPUS:85165103559

SN - 2405-8440

VL - 9

JO - Heliyon

JF - Heliyon

IS - 7

M1 - e18300

ER -

Enhancement of oxygen sensing performance of metalloporphyrin film modified with nano Al₂O₃ powder

Abstract

Keywords

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