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Enhancement of discharge and deposition rate by imposed pulse current during the cathodic arc deposition of ta-C films

  • Jian Hu
  • , Xiubo Tian*
  • , Hongye Liu
  • , Chunzhi Gong
  • , Benfu Wang
  • *Corresponding author for this work
  • Harbin Institute of Technology
  • Shenzhen Jinzhou Precision Technology Corp.
  • CRRC Corporation Limited

Research output: Contribution to journalArticlepeer-review

Abstract

The deposition rate of ta-C films was increased by imposed pulse cathodic arc deposition (IP-CAD). The arc discharge behavior, deposition rate and micro-hardness of the ta-C films were investigated at average arc currents (Iaverage) ranging from 60 A to 100 A. The average substrate current density of IP-CAD was higher than that of DC-CAD at the same Iaverage. The optical emission spectra demonstrated that a dramatic increase in the evaporation rate of both carbon atoms and ions were achieved by imposing high pulsed current with Iaverage of 80 A. As the IAverage increased from 60 A to 100 A, the deposition rate increased by about 110% for the IP-CAD and by 33% for DC-CAD. This might be attributed to the cooperative actions of high evaporation rate of the carbon, large arc pressure near the arc spots and the focusing effect induce by high current. As compared to DC-CAD, the IP-CAD mode led to smaller concentration of sp3 (44%) than DC-CAD (59%) at the IAverage of 80 A. However, the IP-CAD ta-C films exhibited higher micro-hardness (~44.7 GPa) than that of DC-CAD (24 GPa). A preferable toughness was simultaneously obtained for IP-CAD.

Original languageEnglish
Article number110515
JournalVacuum
Volume193
DOIs
StatePublished - Nov 2021

Keywords

  • Average arc current
  • Deposition rate
  • Imposed pulse cathodic arc deposition
  • Micro-hardness
  • Ta-C films

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