Enhanced stability and electrochemical investigations of Ni/ZSM-5 catalyst layer on nickel-based anodes for ammonia-fed solid oxide fuel cells

Ammonia-fed solid oxide fuel cell (SOFC) is a promising clean energy technique with distinctive advantages of zero-carbon emission, easy storage, and high efficiency. However, the typical nickel anode for SOFC is susceptible to structural change and performance degradation under an ammonia environment, particularly at reduced operating temperatures. In addition, obtaining a deep understanding of the individual electrode processes is demanded for the rational design and optimization of NH₃–SOFCs. This work enhances the cell performance and durability of ammonia-fed SOFCs by utilizing a cost-effective ammonia decomposition catalyst (Ni/Na-ZSM). The electrode processes are investigated quantitively using distributed relaxation time (DRT) and equivalent circuit model (ECM) analysis. Accelerated degradation tests are conducted for the NH₃-based SOFC cells by thermal cycling at operational temperatures of 700 °C-650 °C. Compared to the conventional cell, the cell with the Ni/Na-ZSM catalyst exhibits improved cell performance and five times less decay. In situ measurements and impedance analysis combined with microstructural characterization reveal that the durability enhancement is probably ascribed to protecting the structure of the three-phase boundaries (TPBs), which maintains a stable resistance of the TPB charge transfer processes during the temperature cycling.