Enhanced pyroelectric property in (1-x)(Bi0.5Na 0.5)TiO3-xBa(Zr0.055Ti0.945)O 3: Role of morphotropic phase boundary and ferroelectric- antiferroelectric phase transition

Feifei Guo; Bin Yang; Shantao Zhang; Fengmin Wu; Danqing Liu; Pingan Hu; Ye Sun; Dali Wang; Wenwu Cao

doi:10.1063/1.4828675

Enhanced pyroelectric property in (1-x)(Bi_0.5Na _0.5)TiO₃-xBa(Zr_0.055Ti_0.945)O ₃: Role of morphotropic phase boundary and ferroelectric- antiferroelectric phase transition

Feifei Guo
, Bin Yang
, Shantao Zhang
, Fengmin Wu
, Danqing Liu
, Pingan Hu
, Ye Sun
, Dali Wang
, Wenwu Cao

School of Instrumentation Science and Engineering

Harbin Institute of Technology
Nanjing University
School of Chemistry and Chemical Engineering, Harbin Institute of Technology
Harbin Institute of Technology
Pennsylvania State University

Research output: Contribution to journal › Article › peer-review

92 Scopus citations

Abstract

(1-x)(Bi_0.5Na_0.5)TiO₃-xBa(Zr _0.055Ti_0.945)O₃ (0 ≤ x ≤ 0.12) lead-free ceramics have been prepared and the morphotropic phase boundary (MPB) is confirmed to be x = 0.06-0.09. The MPB composition x = 0.07 shows enhanced pyroelectric properties from room temperature (RT) to the depolarization temperature T_d (87°C), with the pyroelectric coefficient p = 0.057 μC/cm²°C and the figures of merit F_i = 203 pm/V, F_v = 0.022 m²/C, and F_d = 10.5 μPa^-1/2 at RT and the highest pyroelectric coefficient of 2.21 μC/cm²°C near T_d. These values are superior to other lead-based/lead-free pyroelectric ceramics. Enhanced pyroelectric properties can be explained by the effects of MPB and ferroelectric- antiferroelectric phase transition.

Original language	English
Article number	182906
Journal	Applied Physics Letters
Volume	103
Issue number	18
DOIs	https://doi.org/10.1063/1.4828675
State	Published - 28 Oct 2013

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@article{3409b4c267b04a38a87b654460f193f2,

title = "Enhanced pyroelectric property in (1-x)(Bi0.5Na 0.5)TiO3-xBa(Zr0.055Ti0.945)O 3: Role of morphotropic phase boundary and ferroelectric- antiferroelectric phase transition",

abstract = "(1-x)(Bi0.5Na0.5)TiO3-xBa(Zr 0.055Ti0.945)O3 (0 ≤ x ≤ 0.12) lead-free ceramics have been prepared and the morphotropic phase boundary (MPB) is confirmed to be x = 0.06-0.09. The MPB composition x = 0.07 shows enhanced pyroelectric properties from room temperature (RT) to the depolarization temperature Td (87°C), with the pyroelectric coefficient p = 0.057 μC/cm2°C and the figures of merit Fi = 203 pm/V, Fv = 0.022 m2/C, and Fd = 10.5 μPa-1/2 at RT and the highest pyroelectric coefficient of 2.21 μC/cm2°C near Td. These values are superior to other lead-based/lead-free pyroelectric ceramics. Enhanced pyroelectric properties can be explained by the effects of MPB and ferroelectric- antiferroelectric phase transition.",

author = "Feifei Guo and Bin Yang and Shantao Zhang and Fengmin Wu and Danqing Liu and Pingan Hu and Ye Sun and Dali Wang and Wenwu Cao",

year = "2013",

month = oct,

day = "28",

doi = "10.1063/1.4828675",

language = "英语",

volume = "103",

journal = "Applied Physics Letters",

issn = "0003-6951",

publisher = "American Institute of Physics",

number = "18",

}

TY - JOUR

T1 - Enhanced pyroelectric property in (1-x)(Bi0.5Na 0.5)TiO3-xBa(Zr0.055Ti0.945)O 3

T2 - Role of morphotropic phase boundary and ferroelectric- antiferroelectric phase transition

AU - Guo, Feifei

AU - Yang, Bin

AU - Zhang, Shantao

AU - Wu, Fengmin

AU - Liu, Danqing

AU - Hu, Pingan

AU - Sun, Ye

AU - Wang, Dali

AU - Cao, Wenwu

PY - 2013/10/28

Y1 - 2013/10/28

N2 - (1-x)(Bi0.5Na0.5)TiO3-xBa(Zr 0.055Ti0.945)O3 (0 ≤ x ≤ 0.12) lead-free ceramics have been prepared and the morphotropic phase boundary (MPB) is confirmed to be x = 0.06-0.09. The MPB composition x = 0.07 shows enhanced pyroelectric properties from room temperature (RT) to the depolarization temperature Td (87°C), with the pyroelectric coefficient p = 0.057 μC/cm2°C and the figures of merit Fi = 203 pm/V, Fv = 0.022 m2/C, and Fd = 10.5 μPa-1/2 at RT and the highest pyroelectric coefficient of 2.21 μC/cm2°C near Td. These values are superior to other lead-based/lead-free pyroelectric ceramics. Enhanced pyroelectric properties can be explained by the effects of MPB and ferroelectric- antiferroelectric phase transition.

AB - (1-x)(Bi0.5Na0.5)TiO3-xBa(Zr 0.055Ti0.945)O3 (0 ≤ x ≤ 0.12) lead-free ceramics have been prepared and the morphotropic phase boundary (MPB) is confirmed to be x = 0.06-0.09. The MPB composition x = 0.07 shows enhanced pyroelectric properties from room temperature (RT) to the depolarization temperature Td (87°C), with the pyroelectric coefficient p = 0.057 μC/cm2°C and the figures of merit Fi = 203 pm/V, Fv = 0.022 m2/C, and Fd = 10.5 μPa-1/2 at RT and the highest pyroelectric coefficient of 2.21 μC/cm2°C near Td. These values are superior to other lead-based/lead-free pyroelectric ceramics. Enhanced pyroelectric properties can be explained by the effects of MPB and ferroelectric- antiferroelectric phase transition.

UR - https://www.scopus.com/pages/publications/84889665237

U2 - 10.1063/1.4828675

DO - 10.1063/1.4828675

M3 - 文章

AN - SCOPUS:84889665237

SN - 0003-6951

VL - 103

JO - Applied Physics Letters

JF - Applied Physics Letters

IS - 18

M1 - 182906

ER -

Enhanced pyroelectric property in (1-x)(Bi_0.5Na _0.5)TiO₃-xBa(Zr_0.055Ti_0.945)O ₃: Role of morphotropic phase boundary and ferroelectric- antiferroelectric phase transition

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