Energy storage performance of Nd3+-doped BiFeO3–BaTiO3-based lead-free ceramics

Amir Khesro; Fawad Ahmad Khan; Raz Muhammad; Asif Ali; Majid Khan; Dawei Wang

doi:10.1016/j.ceramint.2022.06.260

Energy storage performance of Nd³⁺-doped BiFeO₃–BaTiO₃-based lead-free ceramics

Amir Khesro^*
, Fawad Ahmad Khan
, Raz Muhammad
, Asif Ali
, Majid Khan
, Dawei Wang^*

^*Corresponding author for this work

Abdul Wali Khan University Mardan
Shenzhen Institute of Advanced Technology

Research output: Contribution to journal › Article › peer-review

41 Scopus citations

Abstract

Lead-free ceramics 0.7(Bi_1-xNd_x)[Fe_0.95(Li_0.5Nb_0.5)_0.05]O₃-0.3BaTiO₃+0.1 wt% MnO₂ (x = 0–0.05) solid solutions were synthesized through a solid state sintering route. Phase analysis showed the formation of a single/mixed perovskite structure for all samples. A morphotropic phase boundary between rhombohedral R3c and cubic Pm3‾m appeared in all the samples. The microstructure analysis revealed well-densified ceramics with clear grains and grain boundaries. The dielectric measurement showed broadened and frequency-dependent dielectric maxima, indicating relaxor behavior. With an increase in Nd³⁺ concentration, the temperature of maximum relative permittivity (T_m) shifted from 564 °C to 330 °C (x = 0.05). The breakdown strength (BDS) was significantly enhanced from 200 kV/cm (x = 0) to 290 kV/cm (x = 0.03). A maximum recoverable energy (W_rec = 3.2 J/cm³) and a high conversion efficiency (η = 73.7%) was achieved for sample x = 0.03, showing promise for use in pulse power systems.

Original language	English
Pages (from-to)	29938-29943
Number of pages	6
Journal	Ceramics International
Volume	48
Issue number	20
DOIs	https://doi.org/10.1016/j.ceramint.2022.06.260
State	Published - 15 Oct 2022
Externally published	Yes

Keywords

Bismuth ferrite
Energy storage
Ferroelectric
Lead-free dielectric

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10.1016/j.ceramint.2022.06.260

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@article{7cb49b339b9642529432e2e9fdde4540,

title = "Energy storage performance of Nd3+-doped BiFeO3–BaTiO3-based lead-free ceramics",

abstract = "Lead-free ceramics 0.7(Bi1-xNdx)[Fe0.95(Li0.5Nb0.5)0.05]O3-0.3BaTiO3+0.1 wt\% MnO2 (x = 0–0.05) solid solutions were synthesized through a solid state sintering route. Phase analysis showed the formation of a single/mixed perovskite structure for all samples. A morphotropic phase boundary between rhombohedral R3c and cubic Pm3‾m appeared in all the samples. The microstructure analysis revealed well-densified ceramics with clear grains and grain boundaries. The dielectric measurement showed broadened and frequency-dependent dielectric maxima, indicating relaxor behavior. With an increase in Nd3+ concentration, the temperature of maximum relative permittivity (Tm) shifted from 564 °C to 330 °C (x = 0.05). The breakdown strength (BDS) was significantly enhanced from 200 kV/cm (x = 0) to 290 kV/cm (x = 0.03). A maximum recoverable energy (Wrec = 3.2 J/cm3) and a high conversion efficiency (η = 73.7\%) was achieved for sample x = 0.03, showing promise for use in pulse power systems.",

keywords = "Bismuth ferrite, Energy storage, Ferroelectric, Lead-free dielectric",

author = "Amir Khesro and Khan, \{Fawad Ahmad\} and Raz Muhammad and Asif Ali and Majid Khan and Dawei Wang",

note = "Publisher Copyright: {\textcopyright} 2022 Elsevier Ltd and Techna Group S.r.l.",

year = "2022",

month = oct,

day = "15",

doi = "10.1016/j.ceramint.2022.06.260",

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}

TY - JOUR

T1 - Energy storage performance of Nd3+-doped BiFeO3–BaTiO3-based lead-free ceramics

AU - Khesro, Amir

AU - Khan, Fawad Ahmad

AU - Muhammad, Raz

AU - Ali, Asif

AU - Khan, Majid

AU - Wang, Dawei

PY - 2022/10/15

Y1 - 2022/10/15

N2 - Lead-free ceramics 0.7(Bi1-xNdx)[Fe0.95(Li0.5Nb0.5)0.05]O3-0.3BaTiO3+0.1 wt% MnO2 (x = 0–0.05) solid solutions were synthesized through a solid state sintering route. Phase analysis showed the formation of a single/mixed perovskite structure for all samples. A morphotropic phase boundary between rhombohedral R3c and cubic Pm3‾m appeared in all the samples. The microstructure analysis revealed well-densified ceramics with clear grains and grain boundaries. The dielectric measurement showed broadened and frequency-dependent dielectric maxima, indicating relaxor behavior. With an increase in Nd3+ concentration, the temperature of maximum relative permittivity (Tm) shifted from 564 °C to 330 °C (x = 0.05). The breakdown strength (BDS) was significantly enhanced from 200 kV/cm (x = 0) to 290 kV/cm (x = 0.03). A maximum recoverable energy (Wrec = 3.2 J/cm3) and a high conversion efficiency (η = 73.7%) was achieved for sample x = 0.03, showing promise for use in pulse power systems.

AB - Lead-free ceramics 0.7(Bi1-xNdx)[Fe0.95(Li0.5Nb0.5)0.05]O3-0.3BaTiO3+0.1 wt% MnO2 (x = 0–0.05) solid solutions were synthesized through a solid state sintering route. Phase analysis showed the formation of a single/mixed perovskite structure for all samples. A morphotropic phase boundary between rhombohedral R3c and cubic Pm3‾m appeared in all the samples. The microstructure analysis revealed well-densified ceramics with clear grains and grain boundaries. The dielectric measurement showed broadened and frequency-dependent dielectric maxima, indicating relaxor behavior. With an increase in Nd3+ concentration, the temperature of maximum relative permittivity (Tm) shifted from 564 °C to 330 °C (x = 0.05). The breakdown strength (BDS) was significantly enhanced from 200 kV/cm (x = 0) to 290 kV/cm (x = 0.03). A maximum recoverable energy (Wrec = 3.2 J/cm3) and a high conversion efficiency (η = 73.7%) was achieved for sample x = 0.03, showing promise for use in pulse power systems.

KW - Bismuth ferrite

KW - Energy storage

KW - Ferroelectric

KW - Lead-free dielectric

UR - https://www.scopus.com/pages/publications/85133681101

U2 - 10.1016/j.ceramint.2022.06.260

DO - 10.1016/j.ceramint.2022.06.260

M3 - 文章

AN - SCOPUS:85133681101

SN - 0272-8842

VL - 48

SP - 29938

EP - 29943

JO - Ceramics International

JF - Ceramics International

IS - 20

ER -

Energy storage performance of Nd³⁺-doped BiFeO₃–BaTiO₃-based lead-free ceramics

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Keywords

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