Energy storage and thermodynamics of PNZST thick films with coexisting antiferroelectric and ferroelectric phases

Quan Liang Zhao; Yi Kai Wang; Guang Ping He; Jie Jian Di; Lei Zhao; Ting Ting Su; Meng Ying Zhang; Zhi Ling Hou; Dawei Wang

doi:10.1111/ijac.13642

Energy storage and thermodynamics of PNZST thick films with coexisting antiferroelectric and ferroelectric phases

Quan Liang Zhao^*
, Yi Kai Wang
, Guang Ping He
, Jie Jian Di
, Lei Zhao
, Ting Ting Su
, Meng Ying Zhang
, Zhi Ling Hou
, Dawei Wang^*

^*Corresponding author for this work

North China University of Technology
Beijing University of Chemical Technology
University of Sheffield

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

Pb_0.99Nb_0.02(Zr_0.85Sn_0.13Ti_0.02)O₃ (PNZST) antiferroelectric (AFE) thick films are successfully deposited on silicon-based Pt and LaNiO₃ electrodes by a sol-gel method. The coexistence of ferroelectric (FE) and AFE phases are revealed in PNZST films by XRD, electric-induced hysteresis loops, dielectric, and leakage current properties. Comparing with PNZST/Pt film, larger recoverable energy density and efficiency are obtained in PNZST/LaNiO₃ film due to the lower FE phase proportion. It is analyzed and demonstrated by a thermodynamic model of AFE and FE coexistence system. In addition, the fatigue behaviors of both AFE films are also affected by the proportion of the coexisting FE phase. PNZST/LaNiO₃ film exhibits good fatigue resistance on energy storage even after 10¹⁰ switching cycles, which is attractive to pulsed power applications.

Original language	English
Pages (from-to)	154-161
Number of pages	8
Journal	International Journal of Applied Ceramic Technology
Volume	18
Issue number	1
DOIs	https://doi.org/10.1111/ijac.13642
State	Published - 1 Jan 2021
Externally published	Yes

Keywords

antiferroelectric
electrodes
thermodynamics
thick films

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10.1111/ijac.13642

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@article{c5b8896e0d9a47019dfffe632bbb5563,

title = "Energy storage and thermodynamics of PNZST thick films with coexisting antiferroelectric and ferroelectric phases",

abstract = "Pb0.99Nb0.02(Zr0.85Sn0.13Ti0.02)O3 (PNZST) antiferroelectric (AFE) thick films are successfully deposited on silicon-based Pt and LaNiO3 electrodes by a sol-gel method. The coexistence of ferroelectric (FE) and AFE phases are revealed in PNZST films by XRD, electric-induced hysteresis loops, dielectric, and leakage current properties. Comparing with PNZST/Pt film, larger recoverable energy density and efficiency are obtained in PNZST/LaNiO3 film due to the lower FE phase proportion. It is analyzed and demonstrated by a thermodynamic model of AFE and FE coexistence system. In addition, the fatigue behaviors of both AFE films are also affected by the proportion of the coexisting FE phase. PNZST/LaNiO3 film exhibits good fatigue resistance on energy storage even after 1010 switching cycles, which is attractive to pulsed power applications.",

keywords = "antiferroelectric, electrodes, thermodynamics, thick films",

author = "Zhao, \{Quan Liang\} and Wang, \{Yi Kai\} and He, \{Guang Ping\} and Di, \{Jie Jian\} and Lei Zhao and Su, \{Ting Ting\} and Zhang, \{Meng Ying\} and Hou, \{Zhi Ling\} and Dawei Wang",

note = "Publisher Copyright: {\textcopyright} 2020 The American Ceramic Society",

year = "2021",

month = jan,

day = "1",

doi = "10.1111/ijac.13642",

language = "英语",

volume = "18",

pages = "154--161",

journal = "International Journal of Applied Ceramic Technology",

issn = "1546-542X",

publisher = "Wiley-Blackwell",

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}

TY - JOUR

T1 - Energy storage and thermodynamics of PNZST thick films with coexisting antiferroelectric and ferroelectric phases

AU - Zhao, Quan Liang

AU - Wang, Yi Kai

AU - He, Guang Ping

AU - Di, Jie Jian

AU - Zhao, Lei

AU - Su, Ting Ting

AU - Zhang, Meng Ying

AU - Hou, Zhi Ling

AU - Wang, Dawei

PY - 2021/1/1

Y1 - 2021/1/1

N2 - Pb0.99Nb0.02(Zr0.85Sn0.13Ti0.02)O3 (PNZST) antiferroelectric (AFE) thick films are successfully deposited on silicon-based Pt and LaNiO3 electrodes by a sol-gel method. The coexistence of ferroelectric (FE) and AFE phases are revealed in PNZST films by XRD, electric-induced hysteresis loops, dielectric, and leakage current properties. Comparing with PNZST/Pt film, larger recoverable energy density and efficiency are obtained in PNZST/LaNiO3 film due to the lower FE phase proportion. It is analyzed and demonstrated by a thermodynamic model of AFE and FE coexistence system. In addition, the fatigue behaviors of both AFE films are also affected by the proportion of the coexisting FE phase. PNZST/LaNiO3 film exhibits good fatigue resistance on energy storage even after 1010 switching cycles, which is attractive to pulsed power applications.

AB - Pb0.99Nb0.02(Zr0.85Sn0.13Ti0.02)O3 (PNZST) antiferroelectric (AFE) thick films are successfully deposited on silicon-based Pt and LaNiO3 electrodes by a sol-gel method. The coexistence of ferroelectric (FE) and AFE phases are revealed in PNZST films by XRD, electric-induced hysteresis loops, dielectric, and leakage current properties. Comparing with PNZST/Pt film, larger recoverable energy density and efficiency are obtained in PNZST/LaNiO3 film due to the lower FE phase proportion. It is analyzed and demonstrated by a thermodynamic model of AFE and FE coexistence system. In addition, the fatigue behaviors of both AFE films are also affected by the proportion of the coexisting FE phase. PNZST/LaNiO3 film exhibits good fatigue resistance on energy storage even after 1010 switching cycles, which is attractive to pulsed power applications.

KW - antiferroelectric

KW - electrodes

KW - thermodynamics

KW - thick films

UR - https://www.scopus.com/pages/publications/85093986102

U2 - 10.1111/ijac.13642

DO - 10.1111/ijac.13642

M3 - 文章

AN - SCOPUS:85093986102

SN - 1546-542X

VL - 18

SP - 154

EP - 161

JO - International Journal of Applied Ceramic Technology

JF - International Journal of Applied Ceramic Technology

IS - 1

ER -

Energy storage and thermodynamics of PNZST thick films with coexisting antiferroelectric and ferroelectric phases

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Keywords

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