Electrosynthesis of H₂O₂ through a two-electron oxygen reduction reaction by carbon based catalysts: From mechanism, catalyst design to electrode fabrication

Hydrogen peroxide (H₂O₂) is an efficient oxidant with multiple uses ranging from chemical synthesis to wastewater treatment. The in-situ H₂O₂ production via a two-electron oxygen reduction reaction (ORR) will bring H₂O₂ beyond its current applications. The development of carbon materials offers the hope for obtaining inexpensive and high-performance alternatives to substitute noble-metal catalysts in order to provide a full and comprehensive picture of the current state of the art treatments and inspire new research in this area. Herein, the most up-to-date findings in theoretical predictions, synthetic methodologies, and experimental investigations of carbon-based catalysts are systematically summarized. Various electrode fabrication and modification methods were also introduced and compared, along with our original research on the air-breathing cathode and three-phase interface theory inside a porous electrode. In addition, our current understanding of the challenges, future directions, and suggestions on the carbon-based catalyst designs and electrode fabrication are highlighted.