Electrodeposition of Cu-Li alloy from room temperature ionic liquid 1-butyl-3-methylimidazolium tetrafluoroborate

Peixia Yang; Yanbiao Zhao; Caina Su; Kaijian Yang; Bo Yan; Maozhong An

doi:10.1016/j.electacta.2012.09.103

Electrodeposition of Cu-Li alloy from room temperature ionic liquid 1-butyl-3-methylimidazolium tetrafluoroborate

Peixia Yang
, Yanbiao Zhao
, Caina Su
, Kaijian Yang
, Bo Yan
, Maozhong An^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

34 Scopus citations

Abstract

Electrodeposition of Cu-Li alloy from 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIm][BF₄]) ionic liquid was investigated. The cyclic voltammetry behaviors of [BMIm][BF₄] containing Cu(II), Li(I), and mixtures of Cu(II) and Li(I) were studied at a copper working electrode, separately. The Cu-Li alloy produced by direct current electrodeposition was characterized by inductively coupled plasma atomic emission spectrometry (ICP), X-ray photoelectron spectroscopy (XPS), and scanning electron microscope (SEM). The function of 2-butyne-1,4-diol was studied by linear sweep voltammetry. The result shows that the 2-butyne-1,4-diol could improve Li content in deposit, and make the Cu-Li alloy deposits denser and finer.

Original language	English
Pages (from-to)	203-207
Number of pages	5
Journal	Electrochimica Acta
Volume	88
DOIs	https://doi.org/10.1016/j.electacta.2012.09.103
State	Published - 15 Jan 2013
Externally published	Yes

Keywords

1-Butyl-3-methylimidazolium tetrafluoroborate
2-Butyne-1,4-diol
Cu-Li alloy
Electrodeposition
Room temperature ionic liquid

Access to Document

10.1016/j.electacta.2012.09.103

Cite this

@article{3cc2d46c597a4495a5e675b9b413709d,

title = "Electrodeposition of Cu-Li alloy from room temperature ionic liquid 1-butyl-3-methylimidazolium tetrafluoroborate",

abstract = "Electrodeposition of Cu-Li alloy from 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIm][BF4]) ionic liquid was investigated. The cyclic voltammetry behaviors of [BMIm][BF4] containing Cu(II), Li(I), and mixtures of Cu(II) and Li(I) were studied at a copper working electrode, separately. The Cu-Li alloy produced by direct current electrodeposition was characterized by inductively coupled plasma atomic emission spectrometry (ICP), X-ray photoelectron spectroscopy (XPS), and scanning electron microscope (SEM). The function of 2-butyne-1,4-diol was studied by linear sweep voltammetry. The result shows that the 2-butyne-1,4-diol could improve Li content in deposit, and make the Cu-Li alloy deposits denser and finer.",

keywords = "1-Butyl-3-methylimidazolium tetrafluoroborate, 2-Butyne-1,4-diol, Cu-Li alloy, Electrodeposition, Room temperature ionic liquid",

author = "Peixia Yang and Yanbiao Zhao and Caina Su and Kaijian Yang and Bo Yan and Maozhong An",

year = "2013",

month = jan,

day = "15",

doi = "10.1016/j.electacta.2012.09.103",

language = "英语",

volume = "88",

pages = "203--207",

journal = "Electrochimica Acta",

issn = "0013-4686",

publisher = "Elsevier Ltd",

}

TY - JOUR

T1 - Electrodeposition of Cu-Li alloy from room temperature ionic liquid 1-butyl-3-methylimidazolium tetrafluoroborate

AU - Yang, Peixia

AU - Zhao, Yanbiao

AU - Su, Caina

AU - Yang, Kaijian

AU - Yan, Bo

AU - An, Maozhong

PY - 2013/1/15

Y1 - 2013/1/15

N2 - Electrodeposition of Cu-Li alloy from 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIm][BF4]) ionic liquid was investigated. The cyclic voltammetry behaviors of [BMIm][BF4] containing Cu(II), Li(I), and mixtures of Cu(II) and Li(I) were studied at a copper working electrode, separately. The Cu-Li alloy produced by direct current electrodeposition was characterized by inductively coupled plasma atomic emission spectrometry (ICP), X-ray photoelectron spectroscopy (XPS), and scanning electron microscope (SEM). The function of 2-butyne-1,4-diol was studied by linear sweep voltammetry. The result shows that the 2-butyne-1,4-diol could improve Li content in deposit, and make the Cu-Li alloy deposits denser and finer.

AB - Electrodeposition of Cu-Li alloy from 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIm][BF4]) ionic liquid was investigated. The cyclic voltammetry behaviors of [BMIm][BF4] containing Cu(II), Li(I), and mixtures of Cu(II) and Li(I) were studied at a copper working electrode, separately. The Cu-Li alloy produced by direct current electrodeposition was characterized by inductively coupled plasma atomic emission spectrometry (ICP), X-ray photoelectron spectroscopy (XPS), and scanning electron microscope (SEM). The function of 2-butyne-1,4-diol was studied by linear sweep voltammetry. The result shows that the 2-butyne-1,4-diol could improve Li content in deposit, and make the Cu-Li alloy deposits denser and finer.

KW - 1-Butyl-3-methylimidazolium tetrafluoroborate

KW - 2-Butyne-1,4-diol

KW - Cu-Li alloy

KW - Electrodeposition

KW - Room temperature ionic liquid

UR - https://www.scopus.com/pages/publications/84870349110

U2 - 10.1016/j.electacta.2012.09.103

DO - 10.1016/j.electacta.2012.09.103

M3 - 文章

AN - SCOPUS:84870349110

SN - 0013-4686

VL - 88

SP - 203

EP - 207

JO - Electrochimica Acta

JF - Electrochimica Acta

ER -

Electrodeposition of Cu-Li alloy from room temperature ionic liquid 1-butyl-3-methylimidazolium tetrafluoroborate

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this