Electrochromic multilayer films based on trilacunary Dawson-type polyoxometalate

Guanggang Gao; Lin Xu; Wenju Wang; Zhenqing Wang; Yunfeng Qiu; Enbo Wang

doi:10.1016/j.electacta.2004.08.006

Electrochromic multilayer films based on trilacunary Dawson-type polyoxometalate

Guanggang Gao
, Lin Xu^*
, Wenju Wang
, Zhenqing Wang
, Yunfeng Qiu
, Enbo Wang

^*Corresponding author for this work

Northeast Normal University

Research output: Contribution to journal › Article › peer-review

31 Scopus citations

Abstract

A new ultrathin multilayer film consisting of polyoxometalate (POM) cluster Na₁₂[P₂W₁₅O ₅₆]·18H₂O (P₂W₁₅) and polyallylamine hydrochloride (PAH) were fabricated on quartz and ITO substrates by layer-by-layer self-assembly method. The multilayer films, PSS/PAH/(P ₂W₁₅/PAH)_n, were characterized by UV-vis spectra, cyclic voltammetry (CV) and chronoamperometric (CA) measurements. The electrochromic film exhibits both suitable response time and low power consumption due to the presence of lacunary polyoxometalate, providing valuable information for exploring the potential application of polyoxometalate-based electrochromic materials.

Original language	English
Pages (from-to)	1101-1106
Number of pages	6
Journal	Electrochimica Acta
Volume	50
Issue number	5
DOIs	https://doi.org/10.1016/j.electacta.2004.08.006
State	Published - 15 Jan 2005
Externally published	Yes

Keywords

Electrochromism
Film
Lacunary polyoxometalate
Multilayer
Stability

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10.1016/j.electacta.2004.08.006

Cite this

@article{cd51fa908c9b48fd8299265cb14ba54a,

title = "Electrochromic multilayer films based on trilacunary Dawson-type polyoxometalate",

abstract = "A new ultrathin multilayer film consisting of polyoxometalate (POM) cluster Na12[P2W15O 56]·18H2O (P2W15) and polyallylamine hydrochloride (PAH) were fabricated on quartz and ITO substrates by layer-by-layer self-assembly method. The multilayer films, PSS/PAH/(P 2W15/PAH)n, were characterized by UV-vis spectra, cyclic voltammetry (CV) and chronoamperometric (CA) measurements. The electrochromic film exhibits both suitable response time and low power consumption due to the presence of lacunary polyoxometalate, providing valuable information for exploring the potential application of polyoxometalate-based electrochromic materials.",

keywords = "Electrochromism, Film, Lacunary polyoxometalate, Multilayer, Stability",

author = "Guanggang Gao and Lin Xu and Wenju Wang and Zhenqing Wang and Yunfeng Qiu and Enbo Wang",

year = "2005",

month = jan,

day = "15",

doi = "10.1016/j.electacta.2004.08.006",

language = "英语",

volume = "50",

pages = "1101--1106",

journal = "Electrochimica Acta",

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number = "5",

}

TY - JOUR

T1 - Electrochromic multilayer films based on trilacunary Dawson-type polyoxometalate

AU - Gao, Guanggang

AU - Xu, Lin

AU - Wang, Wenju

AU - Wang, Zhenqing

AU - Qiu, Yunfeng

AU - Wang, Enbo

PY - 2005/1/15

Y1 - 2005/1/15

N2 - A new ultrathin multilayer film consisting of polyoxometalate (POM) cluster Na12[P2W15O 56]·18H2O (P2W15) and polyallylamine hydrochloride (PAH) were fabricated on quartz and ITO substrates by layer-by-layer self-assembly method. The multilayer films, PSS/PAH/(P 2W15/PAH)n, were characterized by UV-vis spectra, cyclic voltammetry (CV) and chronoamperometric (CA) measurements. The electrochromic film exhibits both suitable response time and low power consumption due to the presence of lacunary polyoxometalate, providing valuable information for exploring the potential application of polyoxometalate-based electrochromic materials.

AB - A new ultrathin multilayer film consisting of polyoxometalate (POM) cluster Na12[P2W15O 56]·18H2O (P2W15) and polyallylamine hydrochloride (PAH) were fabricated on quartz and ITO substrates by layer-by-layer self-assembly method. The multilayer films, PSS/PAH/(P 2W15/PAH)n, were characterized by UV-vis spectra, cyclic voltammetry (CV) and chronoamperometric (CA) measurements. The electrochromic film exhibits both suitable response time and low power consumption due to the presence of lacunary polyoxometalate, providing valuable information for exploring the potential application of polyoxometalate-based electrochromic materials.

KW - Electrochromism

KW - Film

KW - Lacunary polyoxometalate

KW - Multilayer

KW - Stability

UR - https://www.scopus.com/pages/publications/10444227451

U2 - 10.1016/j.electacta.2004.08.006

DO - 10.1016/j.electacta.2004.08.006

M3 - 文章

AN - SCOPUS:10444227451

SN - 0013-4686

VL - 50

SP - 1101

EP - 1106

JO - Electrochimica Acta

JF - Electrochimica Acta

IS - 5

ER -

Electrochromic multilayer films based on trilacunary Dawson-type polyoxometalate

Abstract

Keywords

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