Electrochemically generatedN-iodoaminium species as key intermediates for selective methyl sulphonylimination of tertiary amines

Binbin Huang; Chao Yang; Jia Zhou; Wujiong Xia

doi:10.1039/c9cc09869k

Electrochemically generatedN-iodoaminium species as key intermediates for selective methyl sulphonylimination of tertiary amines

Binbin Huang
, Chao Yang
, Jia Zhou^*
, Wujiong Xia

^*Corresponding author for this work

Harbin Institute of Technology

Research output: Contribution to journal › Article › peer-review

43 Scopus citations

Abstract

Reported herein is a straightforward protocol for approachingN-sulphonylamidinesviaan electricity-driven, iodine-mediated cross dehydrogenative condensation (CDC) between sulphonamides and tertiary amines, which features exclusive N-CH₃selectivity for the amine partners. Mechanistic studies indicate that anin situgeneratedN-iodoaminium species serves as the key intermediate.

Original language	English
Pages (from-to)	5010-5013
Number of pages	4
Journal	Chemical Communications
Volume	56
Issue number	37
DOIs	https://doi.org/10.1039/c9cc09869k
State	Published - 7 May 2020
Externally published	Yes

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title = "Electrochemically generatedN-iodoaminium species as key intermediates for selective methyl sulphonylimination of tertiary amines",

abstract = "Reported herein is a straightforward protocol for approachingN-sulphonylamidinesviaan electricity-driven, iodine-mediated cross dehydrogenative condensation (CDC) between sulphonamides and tertiary amines, which features exclusive N-CH3selectivity for the amine partners. Mechanistic studies indicate that anin situgeneratedN-iodoaminium species serves as the key intermediate.",

author = "Binbin Huang and Chao Yang and Jia Zhou and Wujiong Xia",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2020.",

year = "2020",

month = may,

day = "7",

doi = "10.1039/c9cc09869k",

language = "英语",

volume = "56",

pages = "5010--5013",

journal = "Chemical Communications",

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T1 - Electrochemically generatedN-iodoaminium species as key intermediates for selective methyl sulphonylimination of tertiary amines

AU - Huang, Binbin

AU - Yang, Chao

AU - Zhou, Jia

AU - Xia, Wujiong

N1 - Publisher Copyright: © The Royal Society of Chemistry 2020.

PY - 2020/5/7

Y1 - 2020/5/7

N2 - Reported herein is a straightforward protocol for approachingN-sulphonylamidinesviaan electricity-driven, iodine-mediated cross dehydrogenative condensation (CDC) between sulphonamides and tertiary amines, which features exclusive N-CH3selectivity for the amine partners. Mechanistic studies indicate that anin situgeneratedN-iodoaminium species serves as the key intermediate.

AB - Reported herein is a straightforward protocol for approachingN-sulphonylamidinesviaan electricity-driven, iodine-mediated cross dehydrogenative condensation (CDC) between sulphonamides and tertiary amines, which features exclusive N-CH3selectivity for the amine partners. Mechanistic studies indicate that anin situgeneratedN-iodoaminium species serves as the key intermediate.

UR - https://www.scopus.com/pages/publications/85084379795

U2 - 10.1039/c9cc09869k

DO - 10.1039/c9cc09869k

M3 - 文章

C2 - 32242553

AN - SCOPUS:85084379795

SN - 1359-7345

VL - 56

SP - 5010

EP - 5013

JO - Chemical Communications

JF - Chemical Communications

IS - 37

ER -

Electrochemically generatedN-iodoaminium species as key intermediates for selective methyl sulphonylimination of tertiary amines

Abstract

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