Electrochemical synthesis of Ti-Si-B compounds in chloride-fluoride molten salts

S. V. Devyatkin

doi:10.1023/A:1015396006717

Electrochemical synthesis of Ti-Si-B compounds in chloride-fluoride molten salts

S. V. Devyatkin^*

^*Corresponding author for this work

NASU - Vernadsky Institute General and Inorganic Chemistry

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Metals, semiconductors, and their binary and ternary compounds can be produced by electrolyzing molten salts of the components. For a Ti-Si-B system, reduction potentials of all three elements are close, which significantly alleviates the problem. Using thermodynamic calculations, voltammetric measurements, and electrolysis we demonstrate the possibility of producing metal-like refractory compounds. Binary compounds TiB₂, Ti ₅Si₃, and SiB₄ and a new ternary compound Ti₅Si₃B₃ are produced electrochemically.

Original language	English
Pages (from-to)	421-424
Number of pages	4
Journal	Russian Journal of Electrochemistry
Volume	38
Issue number	4
DOIs	https://doi.org/10.1023/A:1015396006717
State	Published - Apr 2002
Externally published	Yes

Access to Document

10.1023/A:1015396006717

Cite this

@article{cd7aac6de2da4b29aa1cadcd3d015fe2,

title = "Electrochemical synthesis of Ti-Si-B compounds in chloride-fluoride molten salts",

abstract = "Metals, semiconductors, and their binary and ternary compounds can be produced by electrolyzing molten salts of the components. For a Ti-Si-B system, reduction potentials of all three elements are close, which significantly alleviates the problem. Using thermodynamic calculations, voltammetric measurements, and electrolysis we demonstrate the possibility of producing metal-like refractory compounds. Binary compounds TiB2, Ti 5Si3, and SiB4 and a new ternary compound Ti5Si3B3 are produced electrochemically.",

author = "Devyatkin, \{S. V.\}",

year = "2002",

month = apr,

doi = "10.1023/A:1015396006717",

language = "英语",

volume = "38",

pages = "421--424",

journal = "Russian Journal of Electrochemistry",

issn = "1023-1935",

publisher = "Pleiades Publishing",

number = "4",

}

TY - JOUR

T1 - Electrochemical synthesis of Ti-Si-B compounds in chloride-fluoride molten salts

AU - Devyatkin, S. V.

PY - 2002/4

Y1 - 2002/4

N2 - Metals, semiconductors, and their binary and ternary compounds can be produced by electrolyzing molten salts of the components. For a Ti-Si-B system, reduction potentials of all three elements are close, which significantly alleviates the problem. Using thermodynamic calculations, voltammetric measurements, and electrolysis we demonstrate the possibility of producing metal-like refractory compounds. Binary compounds TiB2, Ti 5Si3, and SiB4 and a new ternary compound Ti5Si3B3 are produced electrochemically.

AB - Metals, semiconductors, and their binary and ternary compounds can be produced by electrolyzing molten salts of the components. For a Ti-Si-B system, reduction potentials of all three elements are close, which significantly alleviates the problem. Using thermodynamic calculations, voltammetric measurements, and electrolysis we demonstrate the possibility of producing metal-like refractory compounds. Binary compounds TiB2, Ti 5Si3, and SiB4 and a new ternary compound Ti5Si3B3 are produced electrochemically.

UR - https://www.scopus.com/pages/publications/0842347466

U2 - 10.1023/A:1015396006717

DO - 10.1023/A:1015396006717

M3 - 文章

AN - SCOPUS:0842347466

SN - 1023-1935

VL - 38

SP - 421

EP - 424

JO - Russian Journal of Electrochemistry

JF - Russian Journal of Electrochemistry

IS - 4

ER -

Electrochemical synthesis of Ti-Si-B compounds in chloride-fluoride molten salts

Abstract

Access to Document

Other files and links

Fingerprint

Cite this