Electrochemical synthesis of tantalum suicides from chloride-fluoride melts

S. V. Devyatkin

doi:10.1149/08614.0095ecst

Electrochemical synthesis of tantalum suicides from chloride-fluoride melts

S. V. Devyatkin^*

^*Corresponding author for this work

NASU - Vernadsky Institute General and Inorganic Chemistry

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

Abstract

The possibility of the electrochemical synthesis of tantalum suicides in chloride-fluoride melts is examined. Based on thermodynamic calculations and voltammetric studies, it has been proved that this process consists of one stage. It is shown that the ratio of the bulk concentrations of tantalum and silicon in the melt does not determine the stoichiometry of cathodic reduction products. TaiSi powder and coatings have been obtained by electrolysis.

Original language	English
Title of host publication	ECS Transactions
Editors	W. Matthew Reichert, Robert A. Mantz, Paul C. Trulove, Luke M. Haverhals, Elizabeth J. Biddinger, Hugh C. De Long, Alice H. Suroviec, Minoru Mizuhata, Mikito Ueda, Adriana Ispas, Andreas Bund, David P. Durkin
Publisher	Electrochemical Society Inc.
Pages	95-100
Number of pages	6
Edition	14
ISBN (Electronic)	9781607688617
ISBN (Print)	9781510871748
DOIs	https://doi.org/10.1149/08614.0095ecst
State	Published - 2018
Externally published	Yes
Event	Symposium on Molten Salts and Ionic Liquids 21 - AiMES 2018, ECS and SMEQ Joint International Meeting - Cancun, Mexico Duration: 30 Sep 2018 → 4 Oct 2018

Publication series

Name	ECS Transactions
Number	14
Volume	86
ISSN (Print)	1938-6737
ISSN (Electronic)	1938-5862

Conference

Conference	Symposium on Molten Salts and Ionic Liquids 21 - AiMES 2018, ECS and SMEQ Joint International Meeting
Country/Territory	Mexico
City	Cancun
Period	30/09/18 → 4/10/18

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 3 Good Health and Well-being

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10.1149/08614.0095ecst

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Devyatkin, S. V. (2018). Electrochemical synthesis of tantalum suicides from chloride-fluoride melts. In W. M. Reichert, R. A. Mantz, P. C. Trulove, L. M. Haverhals, E. J. Biddinger, H. C. De Long, A. H. Suroviec, M. Mizuhata, M. Ueda, A. Ispas, A. Bund, & D. P. Durkin (Eds.), ECS Transactions (14 ed., pp. 95-100). (ECS Transactions; Vol. 86, No. 14). Electrochemical Society Inc.. https://doi.org/10.1149/08614.0095ecst

Devyatkin, S. V. / Electrochemical synthesis of tantalum suicides from chloride-fluoride melts. ECS Transactions. editor / W. Matthew Reichert ; Robert A. Mantz ; Paul C. Trulove ; Luke M. Haverhals ; Elizabeth J. Biddinger ; Hugh C. De Long ; Alice H. Suroviec ; Minoru Mizuhata ; Mikito Ueda ; Adriana Ispas ; Andreas Bund ; David P. Durkin. 14. ed. Electrochemical Society Inc., 2018. pp. 95-100 (ECS Transactions; 14).

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title = "Electrochemical synthesis of tantalum suicides from chloride-fluoride melts",

abstract = "The possibility of the electrochemical synthesis of tantalum suicides in chloride-fluoride melts is examined. Based on thermodynamic calculations and voltammetric studies, it has been proved that this process consists of one stage. It is shown that the ratio of the bulk concentrations of tantalum and silicon in the melt does not determine the stoichiometry of cathodic reduction products. TaiSi powder and coatings have been obtained by electrolysis.",

author = "Devyatkin, \{S. V.\}",

note = "Publisher Copyright: {\textcopyright} 2018 Electrochemical Society Inc.All rights reserved.; Symposium on Molten Salts and Ionic Liquids 21 - AiMES 2018, ECS and SMEQ Joint International Meeting ; Conference date: 30-09-2018 Through 04-10-2018",

year = "2018",

doi = "10.1149/08614.0095ecst",

language = "英语",

isbn = "9781510871748",

series = "ECS Transactions",

publisher = "Electrochemical Society Inc.",

number = "14",

pages = "95--100",

editor = "Reichert, \{W. Matthew\} and Mantz, \{Robert A.\} and Trulove, \{Paul C.\} and Haverhals, \{Luke M.\} and Biddinger, \{Elizabeth J.\} and \{De Long\}, \{Hugh C.\} and Suroviec, \{Alice H.\} and Minoru Mizuhata and Mikito Ueda and Adriana Ispas and Andreas Bund and Durkin, \{David P.\}",

booktitle = "ECS Transactions",

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Devyatkin, SV 2018, Electrochemical synthesis of tantalum suicides from chloride-fluoride melts. in WM Reichert, RA Mantz, PC Trulove, LM Haverhals, EJ Biddinger, HC De Long, AH Suroviec, M Mizuhata, M Ueda, A Ispas, A Bund & DP Durkin (eds), ECS Transactions. 14 edn, ECS Transactions, no. 14, vol. 86, Electrochemical Society Inc., pp. 95-100, Symposium on Molten Salts and Ionic Liquids 21 - AiMES 2018, ECS and SMEQ Joint International Meeting, Cancun, Mexico, 30/09/18. https://doi.org/10.1149/08614.0095ecst

Electrochemical synthesis of tantalum suicides from chloride-fluoride melts. / Devyatkin, S. V.
ECS Transactions. ed. / W. Matthew Reichert; Robert A. Mantz; Paul C. Trulove; Luke M. Haverhals; Elizabeth J. Biddinger; Hugh C. De Long; Alice H. Suroviec; Minoru Mizuhata; Mikito Ueda; Adriana Ispas; Andreas Bund; David P. Durkin. 14. ed. Electrochemical Society Inc., 2018. p. 95-100 (ECS Transactions; Vol. 86, No. 14).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

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AU - Devyatkin, S. V.

PY - 2018

Y1 - 2018

N2 - The possibility of the electrochemical synthesis of tantalum suicides in chloride-fluoride melts is examined. Based on thermodynamic calculations and voltammetric studies, it has been proved that this process consists of one stage. It is shown that the ratio of the bulk concentrations of tantalum and silicon in the melt does not determine the stoichiometry of cathodic reduction products. TaiSi powder and coatings have been obtained by electrolysis.

AB - The possibility of the electrochemical synthesis of tantalum suicides in chloride-fluoride melts is examined. Based on thermodynamic calculations and voltammetric studies, it has been proved that this process consists of one stage. It is shown that the ratio of the bulk concentrations of tantalum and silicon in the melt does not determine the stoichiometry of cathodic reduction products. TaiSi powder and coatings have been obtained by electrolysis.

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DO - 10.1149/08614.0095ecst

M3 - 会议稿件

AN - SCOPUS:85058306568

SN - 9781510871748

T3 - ECS Transactions

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BT - ECS Transactions

A2 - Reichert, W. Matthew

A2 - Mantz, Robert A.

A2 - Trulove, Paul C.

A2 - Haverhals, Luke M.

A2 - Biddinger, Elizabeth J.

A2 - De Long, Hugh C.

A2 - Suroviec, Alice H.

A2 - Mizuhata, Minoru

A2 - Ueda, Mikito

A2 - Ispas, Adriana

A2 - Bund, Andreas

A2 - Durkin, David P.

PB - Electrochemical Society Inc.

T2 - Symposium on Molten Salts and Ionic Liquids 21 - AiMES 2018, ECS and SMEQ Joint International Meeting

Y2 - 30 September 2018 through 4 October 2018

ER -

Electrochemical synthesis of tantalum suicides from chloride-fluoride melts

Abstract

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