Electrochemical synthesis of NiSi2 from a NaCl-NaF-K2SiF6 melt on a Ni cathode

S. A. Kochetova; A. D. Pisanenko; S. V. Devyatkin

doi:10.1149/06404.0523ecst

Electrochemical synthesis of NiSi₂ from a NaCl-NaF-K₂SiF₆ melt on a Ni cathode

S. A. Kochetova
, A. D. Pisanenko
, S. V. Devyatkin

NASU - Vernadsky Institute General and Inorganic Chemistry

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

7 Scopus citations

Abstract

The aim of this work was to examine the possibility of producing nickel silicides by the electrolysis of molten salts, containing silicon ions, on a nickel cathode. Possibility of electrodeposition of nickel disilicide from molten salts was investigated by thermodynamic calculation, voltametric investigation and electrolysis experiments. The electrochemical behavior of the NaCl-NaF-K₂SiF₆ molten salts system was studied by cyclic voltammetry. The electrolysis was carried out in a NaCl-NaF- K₂SiF₆ melt in a glassy carbon crucible at 720°C in argon atmosphere; a nickel plate was used as the cathode. Cathode products were analyzed by X-ray and JEM-2100F SEM. Coatings of nickel disilicide were deposited from NaCl-NaF-K₂SiF₆ melts on a Ni cathode at 720°C in argon atmosphere.

Original language	English
Title of host publication	Molten Salts and Ionic Liquids 19
Editors	W. Matthew Reichert, Adriana Ispas, Andreas Bund, Hugh C. De Long, Luke M. Haverhals, Minoru Mizuhata, Paul C. Trulove, Robert A. Mantz
Publisher	Electrochemical Society Inc.
Pages	523-527
Number of pages	5
Edition	4
ISBN (Electronic)	9781607685371, 9781607685388, 9781607685395, 9781607685418, 9781607685425, 9781607685432, 9781607685449, 9781607685456, 9781607685463, 9781607685470, 9781607685487, 9781607685494, 9781607685500, 9781607685517, 9781607685524, 9781607685531, 9781607685548
DOIs	https://doi.org/10.1149/06404.0523ecst
State	Published - 2014
Externally published	Yes
Event	19th International Symposium on Molten Salts and Ionic Liquids, MS and IL 2014, part of the Joint Meeting of the 226th ECS Meeting and 29th SMEQ Meeting - Cancun, Mexico Duration: 5 Oct 2014 → 9 Oct 2014

Publication series

Name	ECS Transactions
Number	4
Volume	64
ISSN (Print)	1938-6737
ISSN (Electronic)	1938-5862

Conference

Conference	19th International Symposium on Molten Salts and Ionic Liquids, MS and IL 2014, part of the Joint Meeting of the 226th ECS Meeting and 29th SMEQ Meeting
Country/Territory	Mexico
City	Cancun
Period	5/10/14 → 9/10/14

Access to Document

10.1149/06404.0523ecst

Cite this

Kochetova, S. A., Pisanenko, A. D., & Devyatkin, S. V. (2014). Electrochemical synthesis of NiSi₂ from a NaCl-NaF-K₂SiF₆ melt on a Ni cathode. In W. M. Reichert, A. Ispas, A. Bund, H. C. De Long, L. M. Haverhals, M. Mizuhata, P. C. Trulove, & R. A. Mantz (Eds.), Molten Salts and Ionic Liquids 19 (4 ed., pp. 523-527). (ECS Transactions; Vol. 64, No. 4). Electrochemical Society Inc.. https://doi.org/10.1149/06404.0523ecst

Kochetova, S. A. ; Pisanenko, A. D. ; Devyatkin, S. V. / Electrochemical synthesis of NiSi₂ from a NaCl-NaF-K₂SiF₆ melt on a Ni cathode. Molten Salts and Ionic Liquids 19. editor / W. Matthew Reichert ; Adriana Ispas ; Andreas Bund ; Hugh C. De Long ; Luke M. Haverhals ; Minoru Mizuhata ; Paul C. Trulove ; Robert A. Mantz. 4. ed. Electrochemical Society Inc., 2014. pp. 523-527 (ECS Transactions; 4).

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title = "Electrochemical synthesis of NiSi2 from a NaCl-NaF-K2SiF6 melt on a Ni cathode",

abstract = "The aim of this work was to examine the possibility of producing nickel silicides by the electrolysis of molten salts, containing silicon ions, on a nickel cathode. Possibility of electrodeposition of nickel disilicide from molten salts was investigated by thermodynamic calculation, voltametric investigation and electrolysis experiments. The electrochemical behavior of the NaCl-NaF-K2SiF6 molten salts system was studied by cyclic voltammetry. The electrolysis was carried out in a NaCl-NaF- K2SiF6 melt in a glassy carbon crucible at 720°C in argon atmosphere; a nickel plate was used as the cathode. Cathode products were analyzed by X-ray and JEM-2100F SEM. Coatings of nickel disilicide were deposited from NaCl-NaF-K2SiF6 melts on a Ni cathode at 720°C in argon atmosphere.",

author = "Kochetova, \{S. A.\} and Pisanenko, \{A. D.\} and Devyatkin, \{S. V.\}",

note = "Publisher Copyright: Copyright {\textcopyright} 2014 by The Electrochemical Society. All rights reserved.; 19th International Symposium on Molten Salts and Ionic Liquids, MS and IL 2014, part of the Joint Meeting of the 226th ECS Meeting and 29th SMEQ Meeting ; Conference date: 05-10-2014 Through 09-10-2014",

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doi = "10.1149/06404.0523ecst",

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Kochetova, SA, Pisanenko, AD & Devyatkin, SV 2014, Electrochemical synthesis of NiSi₂ from a NaCl-NaF-K₂SiF₆ melt on a Ni cathode. in WM Reichert, A Ispas, A Bund, HC De Long, LM Haverhals, M Mizuhata, PC Trulove & RA Mantz (eds), Molten Salts and Ionic Liquids 19. 4 edn, ECS Transactions, no. 4, vol. 64, Electrochemical Society Inc., pp. 523-527, 19th International Symposium on Molten Salts and Ionic Liquids, MS and IL 2014, part of the Joint Meeting of the 226th ECS Meeting and 29th SMEQ Meeting, Cancun, Mexico, 5/10/14. https://doi.org/10.1149/06404.0523ecst

Electrochemical synthesis of NiSi₂ from a NaCl-NaF-K₂SiF₆ melt on a Ni cathode. / Kochetova, S. A.; Pisanenko, A. D.; Devyatkin, S. V.
Molten Salts and Ionic Liquids 19. ed. / W. Matthew Reichert; Adriana Ispas; Andreas Bund; Hugh C. De Long; Luke M. Haverhals; Minoru Mizuhata; Paul C. Trulove; Robert A. Mantz. 4. ed. Electrochemical Society Inc., 2014. p. 523-527 (ECS Transactions; Vol. 64, No. 4).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

T1 - Electrochemical synthesis of NiSi2 from a NaCl-NaF-K2SiF6 melt on a Ni cathode

AU - Kochetova, S. A.

AU - Pisanenko, A. D.

AU - Devyatkin, S. V.

PY - 2014

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N2 - The aim of this work was to examine the possibility of producing nickel silicides by the electrolysis of molten salts, containing silicon ions, on a nickel cathode. Possibility of electrodeposition of nickel disilicide from molten salts was investigated by thermodynamic calculation, voltametric investigation and electrolysis experiments. The electrochemical behavior of the NaCl-NaF-K2SiF6 molten salts system was studied by cyclic voltammetry. The electrolysis was carried out in a NaCl-NaF- K2SiF6 melt in a glassy carbon crucible at 720°C in argon atmosphere; a nickel plate was used as the cathode. Cathode products were analyzed by X-ray and JEM-2100F SEM. Coatings of nickel disilicide were deposited from NaCl-NaF-K2SiF6 melts on a Ni cathode at 720°C in argon atmosphere.

AB - The aim of this work was to examine the possibility of producing nickel silicides by the electrolysis of molten salts, containing silicon ions, on a nickel cathode. Possibility of electrodeposition of nickel disilicide from molten salts was investigated by thermodynamic calculation, voltametric investigation and electrolysis experiments. The electrochemical behavior of the NaCl-NaF-K2SiF6 molten salts system was studied by cyclic voltammetry. The electrolysis was carried out in a NaCl-NaF- K2SiF6 melt in a glassy carbon crucible at 720°C in argon atmosphere; a nickel plate was used as the cathode. Cathode products were analyzed by X-ray and JEM-2100F SEM. Coatings of nickel disilicide were deposited from NaCl-NaF-K2SiF6 melts on a Ni cathode at 720°C in argon atmosphere.

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DO - 10.1149/06404.0523ecst

M3 - 会议稿件

AN - SCOPUS:84921386264

T3 - ECS Transactions

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BT - Molten Salts and Ionic Liquids 19

A2 - Reichert, W. Matthew

A2 - Ispas, Adriana

A2 - Bund, Andreas

A2 - De Long, Hugh C.

A2 - Haverhals, Luke M.

A2 - Mizuhata, Minoru

A2 - Trulove, Paul C.

A2 - Mantz, Robert A.

PB - Electrochemical Society Inc.

T2 - 19th International Symposium on Molten Salts and Ionic Liquids, MS and IL 2014, part of the Joint Meeting of the 226th ECS Meeting and 29th SMEQ Meeting

Y2 - 5 October 2014 through 9 October 2014

ER -