Electrochemical synthesis of coatings in the system Ti-Si-B from molten salts

S. V. Devyatkin

doi:10.1016/j.jssc.2003.03.007

Electrochemical synthesis of coatings in the system Ti-Si-B from molten salts

S. V. Devyatkin^*

^*Corresponding author for this work

NASU - Vernadsky Institute General and Inorganic Chemistry

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

Powder and coatings of metal-like refractory compounds (MLRC) can be produced by electrochemical synthesis from molten salts. The stoichiometry of the deposited MLRC was found to correlate with the molar ratio of MLRC component ions in the melts. The system Ti-Si-B is of particular interest in terms of electrochemical synthesis since the titanium, silicon and boron potentials in the melt are close together. The electrochemical synthesis has been investigated in the system NaCl-KCl-NaF-K₂TiF₆-K ₂SiF₆-KBF₄ at 700°C. The opportunity of deposition of new ternary compound in the system Ti-Si-B is shown by the electrochemical synthesis from molten salts.

Original language	English
Pages (from-to)	407-409
Number of pages	3
Journal	Journal of Solid State Chemistry
Volume	177
Issue number	2
DOIs	https://doi.org/10.1016/j.jssc.2003.03.007
State	Published - Feb 2004
Externally published	Yes

Keywords

Electrochemical synthesis
Molten salts
Ti-Si-B

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10.1016/j.jssc.2003.03.007

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title = "Electrochemical synthesis of coatings in the system Ti-Si-B from molten salts",

abstract = "Powder and coatings of metal-like refractory compounds (MLRC) can be produced by electrochemical synthesis from molten salts. The stoichiometry of the deposited MLRC was found to correlate with the molar ratio of MLRC component ions in the melts. The system Ti-Si-B is of particular interest in terms of electrochemical synthesis since the titanium, silicon and boron potentials in the melt are close together. The electrochemical synthesis has been investigated in the system NaCl-KCl-NaF-K2TiF6-K 2SiF6-KBF4 at 700°C. The opportunity of deposition of new ternary compound in the system Ti-Si-B is shown by the electrochemical synthesis from molten salts.",

keywords = "Electrochemical synthesis, Molten salts, Ti-Si-B",

author = "Devyatkin, \{S. V.\}",

year = "2004",

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doi = "10.1016/j.jssc.2003.03.007",

language = "英语",

volume = "177",

pages = "407--409",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

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T1 - Electrochemical synthesis of coatings in the system Ti-Si-B from molten salts

AU - Devyatkin, S. V.

PY - 2004/2

Y1 - 2004/2

N2 - Powder and coatings of metal-like refractory compounds (MLRC) can be produced by electrochemical synthesis from molten salts. The stoichiometry of the deposited MLRC was found to correlate with the molar ratio of MLRC component ions in the melts. The system Ti-Si-B is of particular interest in terms of electrochemical synthesis since the titanium, silicon and boron potentials in the melt are close together. The electrochemical synthesis has been investigated in the system NaCl-KCl-NaF-K2TiF6-K 2SiF6-KBF4 at 700°C. The opportunity of deposition of new ternary compound in the system Ti-Si-B is shown by the electrochemical synthesis from molten salts.

AB - Powder and coatings of metal-like refractory compounds (MLRC) can be produced by electrochemical synthesis from molten salts. The stoichiometry of the deposited MLRC was found to correlate with the molar ratio of MLRC component ions in the melts. The system Ti-Si-B is of particular interest in terms of electrochemical synthesis since the titanium, silicon and boron potentials in the melt are close together. The electrochemical synthesis has been investigated in the system NaCl-KCl-NaF-K2TiF6-K 2SiF6-KBF4 at 700°C. The opportunity of deposition of new ternary compound in the system Ti-Si-B is shown by the electrochemical synthesis from molten salts.

KW - Electrochemical synthesis

KW - Molten salts

KW - Ti-Si-B

UR - https://www.scopus.com/pages/publications/0842287931

U2 - 10.1016/j.jssc.2003.03.007

DO - 10.1016/j.jssc.2003.03.007

M3 - 文章

AN - SCOPUS:0842287931

SN - 0022-4596

VL - 177

SP - 407

EP - 409

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

IS - 2

ER -

Electrochemical synthesis of coatings in the system Ti-Si-B from molten salts

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Keywords

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