Electrochemical oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid catalyzed by bio-inspired NiMn layered double hydroxide

Yide Rigen Bao; Yu Duan; Yong Na

doi:10.1039/d3ta03408a

Electrochemical oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid catalyzed by bio-inspired NiMn layered double hydroxide

Yide Rigen Bao
, Yu Duan
, Yong Na^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering, Harbin Institute of Technology

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

The conversion of 5-hydroxymethylfurfural (HMF) into value-added chemicals represents a sustainable bridge toward renewable carbon sources. Inspired by the function of the manganese framework in the active site of the oxygen evolving complex (OEC) in natural photosynthesis, Ni₁Mn₅-LDH was developed as the most efficient Ni-based electrocatalyst for HMF oxidation to FDCA among the reported materials. A faradaic efficiency of 97% was achieved at 1.4 V (vs. RHE), resulting in FDCA production in a yield of 94.72%. An insight into the reaction pathway indicated that the oxidation of the CH₂OH group to the CHO group was the rate-limiting step during HMF oxidation.

Original language	English
Pages (from-to)	18668-18671
Number of pages	4
Journal	Journal of Materials Chemistry A
Volume	11
Issue number	35
DOIs	https://doi.org/10.1039/d3ta03408a
State	Published - 24 Aug 2023
Externally published	Yes

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@article{1173fedde1084620a3dea35c0c530af6,

title = "Electrochemical oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid catalyzed by bio-inspired NiMn layered double hydroxide",

abstract = "The conversion of 5-hydroxymethylfurfural (HMF) into value-added chemicals represents a sustainable bridge toward renewable carbon sources. Inspired by the function of the manganese framework in the active site of the oxygen evolving complex (OEC) in natural photosynthesis, Ni1Mn5-LDH was developed as the most efficient Ni-based electrocatalyst for HMF oxidation to FDCA among the reported materials. A faradaic efficiency of 97\% was achieved at 1.4 V (vs. RHE), resulting in FDCA production in a yield of 94.72\%. An insight into the reaction pathway indicated that the oxidation of the CH2OH group to the CHO group was the rate-limiting step during HMF oxidation.",

author = "Bao, \{Yide Rigen\} and Yu Duan and Yong Na",

note = "Publisher Copyright: {\textcopyright} 2023 The Royal Society of Chemistry.",

year = "2023",

month = aug,

day = "24",

doi = "10.1039/d3ta03408a",

language = "英语",

volume = "11",

pages = "18668--18671",

journal = "Journal of Materials Chemistry A",

issn = "2050-7488",

publisher = "Royal Society of Chemistry",

number = "35",

}

TY - JOUR

T1 - Electrochemical oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid catalyzed by bio-inspired NiMn layered double hydroxide

AU - Bao, Yide Rigen

AU - Duan, Yu

AU - Na, Yong

PY - 2023/8/24

Y1 - 2023/8/24

N2 - The conversion of 5-hydroxymethylfurfural (HMF) into value-added chemicals represents a sustainable bridge toward renewable carbon sources. Inspired by the function of the manganese framework in the active site of the oxygen evolving complex (OEC) in natural photosynthesis, Ni1Mn5-LDH was developed as the most efficient Ni-based electrocatalyst for HMF oxidation to FDCA among the reported materials. A faradaic efficiency of 97% was achieved at 1.4 V (vs. RHE), resulting in FDCA production in a yield of 94.72%. An insight into the reaction pathway indicated that the oxidation of the CH2OH group to the CHO group was the rate-limiting step during HMF oxidation.

AB - The conversion of 5-hydroxymethylfurfural (HMF) into value-added chemicals represents a sustainable bridge toward renewable carbon sources. Inspired by the function of the manganese framework in the active site of the oxygen evolving complex (OEC) in natural photosynthesis, Ni1Mn5-LDH was developed as the most efficient Ni-based electrocatalyst for HMF oxidation to FDCA among the reported materials. A faradaic efficiency of 97% was achieved at 1.4 V (vs. RHE), resulting in FDCA production in a yield of 94.72%. An insight into the reaction pathway indicated that the oxidation of the CH2OH group to the CHO group was the rate-limiting step during HMF oxidation.

UR - https://www.scopus.com/pages/publications/85170554509

U2 - 10.1039/d3ta03408a

DO - 10.1039/d3ta03408a

M3 - 文章

AN - SCOPUS:85170554509

SN - 2050-7488

VL - 11

SP - 18668

EP - 18671

JO - Journal of Materials Chemistry A

JF - Journal of Materials Chemistry A

IS - 35

ER -

Electrochemical oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid catalyzed by bio-inspired NiMn layered double hydroxide

Abstract

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