Electric/magnetic behaviors of Nd/Ti co-doped BiFeO                         3                          ceramics with morphotropic phase boundary

Hua Ke; Liwei Zhang; Hongjun Zhang; Fangzhe Li; Huijiadai Luo; Lu Cao; Wen Wang; Fuli Wang; Dechang Jia; Yu Zhou

doi:10.1016/j.scriptamat.2019.01.025

Electric/magnetic behaviors of Nd/Ti co-doped BiFeO ₃ ceramics with morphotropic phase boundary

Hua Ke^*
, Liwei Zhang
, Hongjun Zhang
, Fangzhe Li
, Huijiadai Luo
, Lu Cao
, Wen Wang
, Fuli Wang
, Dechang Jia
, Yu Zhou

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

30 Scopus citations

Abstract

Morphotropic phase boundaries (MPB) consisting of rhombohedral, nonpolar orthorhombic and orthorhombic bridging phases were formed within the range of 0.1 ≤ x ≤ 0.2 in Bi _1-x Nd _x Fe _0.97 Ti _0.03 O ₃ ceramics. The intricate phase coexistence was verified by X-ray diffraction refinements, new modes at ~305 cm ⁻¹ in Raman spectra and microstructure analyses. Impedance tests confirmed the MPB ranges via resistance fluctuations and revealed additional arcs from phase boundaries. Ferroelectric and magnetic properties were synchronously improved at MPB resulting in the apparent magnetodielectric effect with a permittivity change rate of ~1.5% at 10000 Oe. Additionally, magnetic domains were reversed at low voltages.

Original language	English
Pages (from-to)	6-11
Number of pages	6
Journal	Scripta Materialia
Volume	164
DOIs	https://doi.org/10.1016/j.scriptamat.2019.01.025
State	Published - 15 Apr 2019

Keywords

Ferroelectric
MPB
Magnetism
Magnetodielectric
Phase constitution

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10.1016/j.scriptamat.2019.01.025

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Ke, H., Zhang, L., Zhang, H., Li, F., Luo, H., Cao, L., Wang, W., Wang, F., Jia, D., & Zhou, Y. (2019). Electric/magnetic behaviors of Nd/Ti co-doped BiFeO ₃ ceramics with morphotropic phase boundary Scripta Materialia, 164, 6-11. https://doi.org/10.1016/j.scriptamat.2019.01.025

@article{232e238ed97940158b5ec3f3d50df3e4,

title = " Electric/magnetic behaviors of Nd/Ti co-doped BiFeO 3 ceramics with morphotropic phase boundary ",

abstract = " Morphotropic phase boundaries (MPB) consisting of rhombohedral, nonpolar orthorhombic and orthorhombic bridging phases were formed within the range of 0.1 ≤ x ≤ 0.2 in Bi 1-x Nd x Fe 0.97 Ti 0.03 O 3 ceramics. The intricate phase coexistence was verified by X-ray diffraction refinements, new modes at \textasciitilde{}305 cm −1 in Raman spectra and microstructure analyses. Impedance tests confirmed the MPB ranges via resistance fluctuations and revealed additional arcs from phase boundaries. Ferroelectric and magnetic properties were synchronously improved at MPB resulting in the apparent magnetodielectric effect with a permittivity change rate of \textasciitilde{}1.5\% at 10000 Oe. Additionally, magnetic domains were reversed at low voltages.",

keywords = "Ferroelectric, MPB, Magnetism, Magnetodielectric, Phase constitution",

author = "Hua Ke and Liwei Zhang and Hongjun Zhang and Fangzhe Li and Huijiadai Luo and Lu Cao and Wen Wang and Fuli Wang and Dechang Jia and Yu Zhou",

note = "Publisher Copyright: {\textcopyright} 2019 Elsevier Ltd",

year = "2019",

month = apr,

day = "15",

doi = "10.1016/j.scriptamat.2019.01.025",

language = "英语",

volume = "164",

pages = "6--11",

journal = "Scripta Materialia",

issn = "1359-6462",

publisher = "Acta Materialia Inc",

}

Ke, H, Zhang, L, Zhang, H, Li, F, Luo, H, Cao, L, Wang, W, Wang, F, Jia, D & Zhou, Y 2019, ' Electric/magnetic behaviors of Nd/Ti co-doped BiFeO ₃ ceramics with morphotropic phase boundary ', Scripta Materialia, vol. 164, pp. 6-11. https://doi.org/10.1016/j.scriptamat.2019.01.025

TY - JOUR

T1 - Electric/magnetic behaviors of Nd/Ti co-doped BiFeO 3 ceramics with morphotropic phase boundary

AU - Ke, Hua

AU - Zhang, Liwei

AU - Zhang, Hongjun

AU - Li, Fangzhe

AU - Luo, Huijiadai

AU - Cao, Lu

AU - Wang, Wen

AU - Wang, Fuli

AU - Jia, Dechang

AU - Zhou, Yu

PY - 2019/4/15

Y1 - 2019/4/15

N2 - Morphotropic phase boundaries (MPB) consisting of rhombohedral, nonpolar orthorhombic and orthorhombic bridging phases were formed within the range of 0.1 ≤ x ≤ 0.2 in Bi 1-x Nd x Fe 0.97 Ti 0.03 O 3 ceramics. The intricate phase coexistence was verified by X-ray diffraction refinements, new modes at ~305 cm −1 in Raman spectra and microstructure analyses. Impedance tests confirmed the MPB ranges via resistance fluctuations and revealed additional arcs from phase boundaries. Ferroelectric and magnetic properties were synchronously improved at MPB resulting in the apparent magnetodielectric effect with a permittivity change rate of ~1.5% at 10000 Oe. Additionally, magnetic domains were reversed at low voltages.

AB - Morphotropic phase boundaries (MPB) consisting of rhombohedral, nonpolar orthorhombic and orthorhombic bridging phases were formed within the range of 0.1 ≤ x ≤ 0.2 in Bi 1-x Nd x Fe 0.97 Ti 0.03 O 3 ceramics. The intricate phase coexistence was verified by X-ray diffraction refinements, new modes at ~305 cm −1 in Raman spectra and microstructure analyses. Impedance tests confirmed the MPB ranges via resistance fluctuations and revealed additional arcs from phase boundaries. Ferroelectric and magnetic properties were synchronously improved at MPB resulting in the apparent magnetodielectric effect with a permittivity change rate of ~1.5% at 10000 Oe. Additionally, magnetic domains were reversed at low voltages.

KW - Ferroelectric

KW - MPB

KW - Magnetism

KW - Magnetodielectric

KW - Phase constitution

UR - https://www.scopus.com/pages/publications/85060446388

U2 - 10.1016/j.scriptamat.2019.01.025

DO - 10.1016/j.scriptamat.2019.01.025

M3 - 文章

AN - SCOPUS:85060446388

SN - 1359-6462

VL - 164

SP - 6

EP - 11

JO - Scripta Materialia

JF - Scripta Materialia

ER -

Electric/magnetic behaviors of Nd/Ti co-doped BiFeO ₃ ceramics with morphotropic phase boundary

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Keywords

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