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Electrical properties of AlN and SiO2 Co-modified barium titanate lead-free piezoelectric ceramics

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Abstract

Ba1-xAlxTi1-ySiyO3-xNx(BAxTS4N) piezoceramics were prepared by solid-state reaction sintering. The effects of AlN and SiO2 co-doping on the phase structure and electrical properties of BaTiO3 ceramics were investigated and analyzed. The ceramics adopt a tetragonal crystal symmetry accompanied by the appearance of secondary phases Ba2TiSi2O8 and Ba4Ti2O27. The results of temperature dependence of dielectric constant indicate that the Curie temperature of BAxTS4N ceramics is independent of doping content. The BAxTS4N ceramic for the composition of x = 3% obtains the optimum ferroelectric properties with the remnant polarization (2Pr) of 14.69 C/cm2 and the maximum piezoelectric coefficient (d33) of 230 pC/N.

Original languageEnglish
Pages (from-to)36-42
Number of pages7
JournalFerroelectrics
Volume490
Issue number1
DOIs
StatePublished - 2 Jan 2016

Keywords

  • Barium titanate
  • co-doping
  • ferroelectric properties
  • piezoelectricity

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