Abstract
Femtosecond dynamics has been recently observed by resonant X-ray Raman scattering (RXRS) after excitation along the dissociative Cl 1 s → 6 σ* resonance of gas phase HCl. In this paper, we show a method to take into account and correct for self-absorption of the elastic peak, in order to allow for quantitative comparison with theory. We have performed measurements on the DCl molecule exhibiting ultrafast nuclear motion. A comparison between HCl and DCl is presented.
| Original language | English |
|---|---|
| Pages (from-to) | 91-94 |
| Number of pages | 4 |
| Journal | Journal of Electron Spectroscopy and Related Phenomena |
| Volume | 155 |
| Issue number | 1-3 |
| DOIs | |
| State | Published - Mar 2007 |
| Externally published | Yes |
Keywords
- DCl
- Elastic peak
- HCl
- Nuclear motion
- RIXS
- RXRS
- Self-absorption
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