Efficient Synthesis of Graphene Nanoscrolls for Fabricating Sulfur-Loaded Cathode and Flexible Hybrid Interlayer toward High-Performance Li-S Batteries

Yi Guo; Gang Zhao; Naiteng Wu; Yun Zhang; Mingwu Xiang; Bo Wang; Heng Liu; Hao Wu

doi:10.1021/acsami.6b13455

Efficient Synthesis of Graphene Nanoscrolls for Fabricating Sulfur-Loaded Cathode and Flexible Hybrid Interlayer toward High-Performance Li-S Batteries

Yi Guo
, Gang Zhao
, Naiteng Wu
, Yun Zhang^*
, Mingwu Xiang
, Bo Wang
, Heng Liu
, Hao Wu

^*Corresponding author for this work

College of Materials Science and Engineering
School of Chemistry and Chemical Engineering, Harbin Institute of Technology

Research output: Contribution to journal › Article › peer-review

86 Scopus citations

Abstract

A modified lyophilization approach is developed and used for highly efficient transformation of 2D graphene oxide sheet into 1D graphene nanoscroll (GNS) with high topological transforming efficiency (∼94%). Because of the unique open tubular structure and large specific surface area (545 m² g^-1), GNS is utilized for the first time as a porous cathode scaffold for encapsulating sulfur with a high loading (81 wt %), and also as a conductive skeleton for assembling MnO₂ nanowires into a flexible free-standing hybrid interlayer, both enabling high-rate and long-life Li-S battery.

Original language	English
Pages (from-to)	34185-34193
Number of pages	9
Journal	ACS Applied Materials and Interfaces
Volume	8
Issue number	50
DOIs	https://doi.org/10.1021/acsami.6b13455
State	Published - 21 Dec 2016
Externally published	Yes

Keywords

free-standing hybrid interlayer
graphene nanoscroll
high sulfur loading
large surface area
lithium sulfur batteries

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10.1021/acsami.6b13455

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title = "Efficient Synthesis of Graphene Nanoscrolls for Fabricating Sulfur-Loaded Cathode and Flexible Hybrid Interlayer toward High-Performance Li-S Batteries",

abstract = "A modified lyophilization approach is developed and used for highly efficient transformation of 2D graphene oxide sheet into 1D graphene nanoscroll (GNS) with high topological transforming efficiency (∼94\%). Because of the unique open tubular structure and large specific surface area (545 m2 g-1), GNS is utilized for the first time as a porous cathode scaffold for encapsulating sulfur with a high loading (81 wt \%), and also as a conductive skeleton for assembling MnO2 nanowires into a flexible free-standing hybrid interlayer, both enabling high-rate and long-life Li-S battery.",

keywords = "free-standing hybrid interlayer, graphene nanoscroll, high sulfur loading, large surface area, lithium sulfur batteries",

author = "Yi Guo and Gang Zhao and Naiteng Wu and Yun Zhang and Mingwu Xiang and Bo Wang and Heng Liu and Hao Wu",

note = "Publisher Copyright: {\textcopyright} 2016 American Chemical Society.",

year = "2016",

month = dec,

day = "21",

doi = "10.1021/acsami.6b13455",

language = "英语",

volume = "8",

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journal = "ACS Applied Materials and Interfaces",

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publisher = "American Chemical Society",

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T1 - Efficient Synthesis of Graphene Nanoscrolls for Fabricating Sulfur-Loaded Cathode and Flexible Hybrid Interlayer toward High-Performance Li-S Batteries

AU - Guo, Yi

AU - Zhao, Gang

AU - Wu, Naiteng

AU - Zhang, Yun

AU - Xiang, Mingwu

AU - Wang, Bo

AU - Liu, Heng

AU - Wu, Hao

PY - 2016/12/21

Y1 - 2016/12/21

N2 - A modified lyophilization approach is developed and used for highly efficient transformation of 2D graphene oxide sheet into 1D graphene nanoscroll (GNS) with high topological transforming efficiency (∼94%). Because of the unique open tubular structure and large specific surface area (545 m2 g-1), GNS is utilized for the first time as a porous cathode scaffold for encapsulating sulfur with a high loading (81 wt %), and also as a conductive skeleton for assembling MnO2 nanowires into a flexible free-standing hybrid interlayer, both enabling high-rate and long-life Li-S battery.

AB - A modified lyophilization approach is developed and used for highly efficient transformation of 2D graphene oxide sheet into 1D graphene nanoscroll (GNS) with high topological transforming efficiency (∼94%). Because of the unique open tubular structure and large specific surface area (545 m2 g-1), GNS is utilized for the first time as a porous cathode scaffold for encapsulating sulfur with a high loading (81 wt %), and also as a conductive skeleton for assembling MnO2 nanowires into a flexible free-standing hybrid interlayer, both enabling high-rate and long-life Li-S battery.

KW - free-standing hybrid interlayer

KW - graphene nanoscroll

KW - high sulfur loading

KW - large surface area

KW - lithium sulfur batteries

UR - https://www.scopus.com/pages/publications/85006958568

U2 - 10.1021/acsami.6b13455

DO - 10.1021/acsami.6b13455

M3 - 文章

AN - SCOPUS:85006958568

SN - 1944-8244

VL - 8

SP - 34185

EP - 34193

JO - ACS Applied Materials and Interfaces

JF - ACS Applied Materials and Interfaces

IS - 50

ER -

Efficient Synthesis of Graphene Nanoscrolls for Fabricating Sulfur-Loaded Cathode and Flexible Hybrid Interlayer toward High-Performance Li-S Batteries

Abstract

Keywords

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