Effects of oxygen vacancies on electric properties of high valence ions Mo/Zr/Ti doped Bi0.85Nd0.15FeO3 ceramics with morphotropic phase boundary

Jingxin Tian; Hongjun Zhang; Liwei Zhang; Dongliang Wang; Yong Huang; Elena Balashova; Boris Krichevtsov; Hua Ke

doi:10.1016/j.mtcomm.2023.106277

Effects of oxygen vacancies on electric properties of high valence ions Mo/Zr/Ti doped Bi_0.85Nd_0.15FeO₃ ceramics with morphotropic phase boundary

Jingxin Tian
, Hongjun Zhang
, Liwei Zhang
, Dongliang Wang
, Yong Huang
, Elena Balashova
, Boris Krichevtsov
, Hua Ke^*

^*Corresponding author for this work

School of Materials Science and Engineering

Harbin Institute of Technology
Harbin Institute of Technology
Harbin Institute of Technology
Harbin University of Science and Technology
The Su Zhou Bohai Microsystem Company Ltd.
Russian Academy of Sciences

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

The effects of oxygen vacancies on electric properties of high valence ions (Mo/Zr/Ti) doped Bi_0.85Nd_0.15FeO₃ (marked as BNFM, BNFZ, BNFT) ceramics with morphotropic phase boundary (MPB) are investigated. MPB structures consisting of rhombohedral, intermediate and orthorhombic phases exist in all samples, which is confirmed by the XRD Rietveld refinements and TEM analyses. The BNFT has the maximum remnant polarization of 34.5 μC/cm² at 180 kV/cm, owing to its lowest paraelectric orthorhombic phase content. XPS and impedance results reveal that the BNFT ceramic has the relatively low oxygen vacancy contents and the largest impedance value, which is beneficial for the ferroelectric test. The best comprehensive properties of BNFT open wide prospects for improving BiFeO₃-based ceramics.

Original language	English
Article number	106277
Journal	Materials Today Communications
Volume	35
DOIs	https://doi.org/10.1016/j.mtcomm.2023.106277
State	Published - Jun 2023

Keywords

BiFeO ceramic
Electric properties
Impedance
MPB
Oxygen vacancy

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@article{758c7b909aae4141800d1f727151222b,

title = "Effects of oxygen vacancies on electric properties of high valence ions Mo/Zr/Ti doped Bi0.85Nd0.15FeO3 ceramics with morphotropic phase boundary",

abstract = "The effects of oxygen vacancies on electric properties of high valence ions (Mo/Zr/Ti) doped Bi0.85Nd0.15FeO3 (marked as BNFM, BNFZ, BNFT) ceramics with morphotropic phase boundary (MPB) are investigated. MPB structures consisting of rhombohedral, intermediate and orthorhombic phases exist in all samples, which is confirmed by the XRD Rietveld refinements and TEM analyses. The BNFT has the maximum remnant polarization of 34.5 μC/cm2 at 180 kV/cm, owing to its lowest paraelectric orthorhombic phase content. XPS and impedance results reveal that the BNFT ceramic has the relatively low oxygen vacancy contents and the largest impedance value, which is beneficial for the ferroelectric test. The best comprehensive properties of BNFT open wide prospects for improving BiFeO3-based ceramics.",

keywords = "BiFeO ceramic, Electric properties, Impedance, MPB, Oxygen vacancy",

author = "Jingxin Tian and Hongjun Zhang and Liwei Zhang and Dongliang Wang and Yong Huang and Elena Balashova and Boris Krichevtsov and Hua Ke",

note = "Publisher Copyright: {\textcopyright} 2023 Elsevier Ltd",

year = "2023",

month = jun,

doi = "10.1016/j.mtcomm.2023.106277",

language = "英语",

volume = "35",

journal = "Materials Today Communications",

issn = "2352-4928",

publisher = "Elsevier Ltd",

}

TY - JOUR

T1 - Effects of oxygen vacancies on electric properties of high valence ions Mo/Zr/Ti doped Bi0.85Nd0.15FeO3 ceramics with morphotropic phase boundary

AU - Tian, Jingxin

AU - Zhang, Hongjun

AU - Zhang, Liwei

AU - Wang, Dongliang

AU - Huang, Yong

AU - Balashova, Elena

AU - Krichevtsov, Boris

AU - Ke, Hua

PY - 2023/6

Y1 - 2023/6

N2 - The effects of oxygen vacancies on electric properties of high valence ions (Mo/Zr/Ti) doped Bi0.85Nd0.15FeO3 (marked as BNFM, BNFZ, BNFT) ceramics with morphotropic phase boundary (MPB) are investigated. MPB structures consisting of rhombohedral, intermediate and orthorhombic phases exist in all samples, which is confirmed by the XRD Rietveld refinements and TEM analyses. The BNFT has the maximum remnant polarization of 34.5 μC/cm2 at 180 kV/cm, owing to its lowest paraelectric orthorhombic phase content. XPS and impedance results reveal that the BNFT ceramic has the relatively low oxygen vacancy contents and the largest impedance value, which is beneficial for the ferroelectric test. The best comprehensive properties of BNFT open wide prospects for improving BiFeO3-based ceramics.

AB - The effects of oxygen vacancies on electric properties of high valence ions (Mo/Zr/Ti) doped Bi0.85Nd0.15FeO3 (marked as BNFM, BNFZ, BNFT) ceramics with morphotropic phase boundary (MPB) are investigated. MPB structures consisting of rhombohedral, intermediate and orthorhombic phases exist in all samples, which is confirmed by the XRD Rietveld refinements and TEM analyses. The BNFT has the maximum remnant polarization of 34.5 μC/cm2 at 180 kV/cm, owing to its lowest paraelectric orthorhombic phase content. XPS and impedance results reveal that the BNFT ceramic has the relatively low oxygen vacancy contents and the largest impedance value, which is beneficial for the ferroelectric test. The best comprehensive properties of BNFT open wide prospects for improving BiFeO3-based ceramics.

KW - BiFeO ceramic

KW - Electric properties

KW - Impedance

KW - MPB

KW - Oxygen vacancy

UR - https://www.scopus.com/pages/publications/85159758951

U2 - 10.1016/j.mtcomm.2023.106277

DO - 10.1016/j.mtcomm.2023.106277

M3 - 文章

AN - SCOPUS:85159758951

SN - 2352-4928

VL - 35

JO - Materials Today Communications

JF - Materials Today Communications

M1 - 106277

ER -

Effects of oxygen vacancies on electric properties of high valence ions Mo/Zr/Ti doped Bi_0.85Nd_0.15FeO₃ ceramics with morphotropic phase boundary

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Keywords

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