Effects of morphotropic phase boundary on the electric behavior of Er/Ti co-doped BiFeO3 ceramics

Liwei Zhang; Hua Ke; Hongjun Zhang; Fangzhe Li; Jinggeng Zhao; Huijiadai Luo; Lu Cao; Gang Zeng; Xiening Li; Wen Wang; Dechang Jia; Yu Zhou

doi:10.1016/j.scriptamat.2018.08.030

Effects of morphotropic phase boundary on the electric behavior of Er/Ti co-doped BiFeO₃ ceramics

Liwei Zhang
, Hua Ke^*
, Hongjun Zhang
, Fangzhe Li
, Jinggeng Zhao
, Huijiadai Luo
, Lu Cao
, Gang Zeng
, Xiening Li
, Wen Wang
, Dechang Jia
, Yu Zhou

^*Corresponding author for this work

Harbin Institute of Technology
Harbin Institute of Technology

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

Morphotropic phase boundaries (MPB) consisting of rhombohedral and orthorhombic phases formed within the range of 0.1 ≤ x ≤ 0.15 in Bi_1-xEr_xFe_0.97Ti_0.03O₃ ceramics. Orthorhombic phase transition was verified by the appearance of a new mode at 310 cm⁻¹ in Raman spectra. Bridging phases as intermedia phases of MPB were rare in Bi_1-xEr_xFe_0.97Ti_0.03O₃. Polarization and permittivity improved at MPB. Moreover, impedance spectroscopy revealed additional arcs with a distinct small polaron conduction mechanism. Er³⁺ ions enhanced magnetic properties and induced a permittivity change at Neel temperature. The magnetodielectric effect resulted in a permittivity change rate of ~1% at 10000 Oe.

Original language	English
Pages (from-to)	71-76
Number of pages	6
Journal	Scripta Materialia
Volume	158
DOIs	https://doi.org/10.1016/j.scriptamat.2018.08.030
State	Published - 1 Jan 2019

Keywords

BiErFeTiO
Electric behavior
MPB
Magnetodielectric
Phase constitution

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10.1016/j.scriptamat.2018.08.030

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@article{31053914cd534915896e93c67ad67221,

title = "Effects of morphotropic phase boundary on the electric behavior of Er/Ti co-doped BiFeO3 ceramics",

abstract = "Morphotropic phase boundaries (MPB) consisting of rhombohedral and orthorhombic phases formed within the range of 0.1 ≤ x ≤ 0.15 in Bi1-xErxFe0.97Ti0.03O3 ceramics. Orthorhombic phase transition was verified by the appearance of a new mode at 310 cm−1 in Raman spectra. Bridging phases as intermedia phases of MPB were rare in Bi1-xErxFe0.97Ti0.03O3. Polarization and permittivity improved at MPB. Moreover, impedance spectroscopy revealed additional arcs with a distinct small polaron conduction mechanism. Er3+ ions enhanced magnetic properties and induced a permittivity change at Neel temperature. The magnetodielectric effect resulted in a permittivity change rate of \textasciitilde{}1\% at 10000 Oe.",

keywords = "BiErFeTiO, Electric behavior, MPB, Magnetodielectric, Phase constitution",

author = "Liwei Zhang and Hua Ke and Hongjun Zhang and Fangzhe Li and Jinggeng Zhao and Huijiadai Luo and Lu Cao and Gang Zeng and Xiening Li and Wen Wang and Dechang Jia and Yu Zhou",

note = "Publisher Copyright: {\textcopyright} 2018 Acta Materialia Inc.",

year = "2019",

month = jan,

day = "1",

doi = "10.1016/j.scriptamat.2018.08.030",

language = "英语",

volume = "158",

pages = "71--76",

journal = "Scripta Materialia",

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TY - JOUR

T1 - Effects of morphotropic phase boundary on the electric behavior of Er/Ti co-doped BiFeO3 ceramics

AU - Zhang, Liwei

AU - Ke, Hua

AU - Zhang, Hongjun

AU - Li, Fangzhe

AU - Zhao, Jinggeng

AU - Luo, Huijiadai

AU - Cao, Lu

AU - Zeng, Gang

AU - Li, Xiening

AU - Wang, Wen

AU - Jia, Dechang

AU - Zhou, Yu

PY - 2019/1/1

Y1 - 2019/1/1

N2 - Morphotropic phase boundaries (MPB) consisting of rhombohedral and orthorhombic phases formed within the range of 0.1 ≤ x ≤ 0.15 in Bi1-xErxFe0.97Ti0.03O3 ceramics. Orthorhombic phase transition was verified by the appearance of a new mode at 310 cm−1 in Raman spectra. Bridging phases as intermedia phases of MPB were rare in Bi1-xErxFe0.97Ti0.03O3. Polarization and permittivity improved at MPB. Moreover, impedance spectroscopy revealed additional arcs with a distinct small polaron conduction mechanism. Er3+ ions enhanced magnetic properties and induced a permittivity change at Neel temperature. The magnetodielectric effect resulted in a permittivity change rate of ~1% at 10000 Oe.

AB - Morphotropic phase boundaries (MPB) consisting of rhombohedral and orthorhombic phases formed within the range of 0.1 ≤ x ≤ 0.15 in Bi1-xErxFe0.97Ti0.03O3 ceramics. Orthorhombic phase transition was verified by the appearance of a new mode at 310 cm−1 in Raman spectra. Bridging phases as intermedia phases of MPB were rare in Bi1-xErxFe0.97Ti0.03O3. Polarization and permittivity improved at MPB. Moreover, impedance spectroscopy revealed additional arcs with a distinct small polaron conduction mechanism. Er3+ ions enhanced magnetic properties and induced a permittivity change at Neel temperature. The magnetodielectric effect resulted in a permittivity change rate of ~1% at 10000 Oe.

KW - BiErFeTiO

KW - Electric behavior

KW - MPB

KW - Magnetodielectric

KW - Phase constitution

UR - https://www.scopus.com/pages/publications/85052474381

U2 - 10.1016/j.scriptamat.2018.08.030

DO - 10.1016/j.scriptamat.2018.08.030

M3 - 文章

AN - SCOPUS:85052474381

SN - 1359-6462

VL - 158

SP - 71

EP - 76

JO - Scripta Materialia

JF - Scripta Materialia

ER -

Effects of morphotropic phase boundary on the electric behavior of Er/Ti co-doped BiFeO₃ ceramics

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Keywords

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