Effects of hydrogen on the crystallization process of Zr41.2Ti13.8Cu12.5Ni10 Be22.5 bulk amorphous alloys

Delin Peng; Jianfei Sun; Jun Shen; Yuyong Chen

Effects of hydrogen on the crystallization process of Zr_41.2Ti_13.8Cu_12.5Ni₁₀ Be_22.5 bulk amorphous alloys

Delin Peng^*
, Jianfei Sun
, Jun Shen
, Yuyong Chen

^*Corresponding author for this work

School of Materials Science and Engineering

Harbin Institute of Technology

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

Zr_41.2Ti_13.8Ni₁₀Cu_12.5 Be_22.5 bulk amorphous alloy was prepared by arc-melting and rapid casting into a copper mould. Hydrogen charging was performed electrochemically in glycerine-phosphoric acid electrolyte. The effects of hydrogen on the crystallization process of Zr-Ti-Cu-Ni-Be bulk amorphous alloy were studied by differential scanning calorimetry (DSC), Kissinger equation and high-resolution transmission electron microscope (HRTEM). It is shown that hydrogen increases the activation energy of the glass transition and crystallization, and retards the nucleation and crystal growth. Moreover, hydrogen charging contributes to the formation of isolated crystals, resulting in the precipitation of fine and uniformly distributed nanocrystallines.

Original language	English
Pages (from-to)	724-727
Number of pages	4
Journal	Xiyou Jinshu Cailiao Yu Gongcheng/Rare Metal Materials and Engineering
Volume	35
Issue number	5
State	Published - May 2006

Keywords

Bulk amorphous alloy
Crystallization process
Hydrogen
Nanocrystallines
Zr-Ti-Cu-Ni-Be

Cite this

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title = "Effects of hydrogen on the crystallization process of Zr41.2Ti13.8Cu12.5Ni10 Be22.5 bulk amorphous alloys",

abstract = "Zr41.2Ti13.8Ni10Cu12.5 Be22.5 bulk amorphous alloy was prepared by arc-melting and rapid casting into a copper mould. Hydrogen charging was performed electrochemically in glycerine-phosphoric acid electrolyte. The effects of hydrogen on the crystallization process of Zr-Ti-Cu-Ni-Be bulk amorphous alloy were studied by differential scanning calorimetry (DSC), Kissinger equation and high-resolution transmission electron microscope (HRTEM). It is shown that hydrogen increases the activation energy of the glass transition and crystallization, and retards the nucleation and crystal growth. Moreover, hydrogen charging contributes to the formation of isolated crystals, resulting in the precipitation of fine and uniformly distributed nanocrystallines.",

keywords = "Bulk amorphous alloy, Crystallization process, Hydrogen, Nanocrystallines, Zr-Ti-Cu-Ni-Be",

author = "Delin Peng and Jianfei Sun and Jun Shen and Yuyong Chen",

year = "2006",

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language = "英语",

volume = "35",

pages = "724--727",

journal = "Xiyou Jinshu Cailiao Yu Gongcheng/Rare Metal Materials and Engineering",

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TY - JOUR

T1 - Effects of hydrogen on the crystallization process of Zr41.2Ti13.8Cu12.5Ni10 Be22.5 bulk amorphous alloys

AU - Peng, Delin

AU - Sun, Jianfei

AU - Shen, Jun

AU - Chen, Yuyong

PY - 2006/5

Y1 - 2006/5

N2 - Zr41.2Ti13.8Ni10Cu12.5 Be22.5 bulk amorphous alloy was prepared by arc-melting and rapid casting into a copper mould. Hydrogen charging was performed electrochemically in glycerine-phosphoric acid electrolyte. The effects of hydrogen on the crystallization process of Zr-Ti-Cu-Ni-Be bulk amorphous alloy were studied by differential scanning calorimetry (DSC), Kissinger equation and high-resolution transmission electron microscope (HRTEM). It is shown that hydrogen increases the activation energy of the glass transition and crystallization, and retards the nucleation and crystal growth. Moreover, hydrogen charging contributes to the formation of isolated crystals, resulting in the precipitation of fine and uniformly distributed nanocrystallines.

AB - Zr41.2Ti13.8Ni10Cu12.5 Be22.5 bulk amorphous alloy was prepared by arc-melting and rapid casting into a copper mould. Hydrogen charging was performed electrochemically in glycerine-phosphoric acid electrolyte. The effects of hydrogen on the crystallization process of Zr-Ti-Cu-Ni-Be bulk amorphous alloy were studied by differential scanning calorimetry (DSC), Kissinger equation and high-resolution transmission electron microscope (HRTEM). It is shown that hydrogen increases the activation energy of the glass transition and crystallization, and retards the nucleation and crystal growth. Moreover, hydrogen charging contributes to the formation of isolated crystals, resulting in the precipitation of fine and uniformly distributed nanocrystallines.

KW - Bulk amorphous alloy

KW - Crystallization process

KW - Hydrogen

KW - Nanocrystallines

KW - Zr-Ti-Cu-Ni-Be

UR - https://www.scopus.com/pages/publications/33745178860

M3 - 文章

AN - SCOPUS:33745178860

SN - 1002-185X

VL - 35

SP - 724

EP - 727

JO - Xiyou Jinshu Cailiao Yu Gongcheng/Rare Metal Materials and Engineering

JF - Xiyou Jinshu Cailiao Yu Gongcheng/Rare Metal Materials and Engineering

IS - 5

ER -

Effects of hydrogen on the crystallization process of Zr_41.2Ti_13.8Cu_12.5Ni₁₀ Be_22.5 bulk amorphous alloys

Abstract

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