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Effect of chain length on low temperature gold-gold bonding by self-assembled monolayers

  • X. F. Ang
  • , Z. Chen
  • , C. C. Wong
  • , J. Wei
  • Nanyang Technological University
  • Agency for Science, Technology and Research, Singapore

Research output: Contribution to journalArticlepeer-review

Abstract

The tensile strength of thermocompression gold joints formed with prior surface coatings of alkanethiol self-assembled monolayers (SAMs) depends on the chain length (n) of the SAM. Enhancement of bond strength is most significant at n=6 while no improvement can be achieved using octadecanethiol (n=18). These contrasting behaviors can be interpreted as a consequence of two dominant roles of alkanethiols that govern the bonding phenomenon, namely, the passivation of gold surfaces and the ease of mechanical and/or thermal displacement.

Original languageEnglish
Article number131913
JournalApplied Physics Letters
Volume92
Issue number13
DOIs
StatePublished - 2008
Externally publishedYes

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