Dopant Occupancy and UV–Vis–NIR Spectroscopy of Sc:Yb:Tm:LiNbO3 in the 300–3000 nm Wavelength Range

Li Dai; Yuning Wang; Ruirun Chen; Shunxiang Yang; Xianbo Han; Chunrui Liu; Yu Shao

doi:10.1002/crat.201900176

Dopant Occupancy and UV–Vis–NIR Spectroscopy of Sc:Yb:Tm:LiNbO₃ in the 300–3000 nm Wavelength Range

Li Dai^*
, Yuning Wang
, Ruirun Chen
, Shunxiang Yang
, Xianbo Han
, Chunrui Liu
, Yu Shao

^*Corresponding author for this work

Harbin University of Science and Technology
Harbin Institute of Technology

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

A series of Sc:Yb:Tm:LiNbO₃ crystals with variable Sc³⁺ (0, 1, 2, and 3 mol%) concentration are grown by the Czochralski method. The effective distribution coefficients of Sc³⁺, Yb³⁺, and Tm³⁺ ions in the Sc:Yb:Tm:LiNbO₃ crystals are determined by inductively coupled plasma atomic emission spectrometer. Sc³⁺ ions distribute uniformly in crystals when Sc³⁺ concentration reaches up to 3 mol%. The influence of Sc³⁺ concentration on the dopant occupancy and defect structure of Sc:Yb:Tm:LiNbO₃ crystals is investigated by IR transmission spectra. Threshold concentration of Sc³⁺ ions in Sc:Yb:Tm:LiNbO₃ crystals is nearly 3 mol%. By analyzing UV–vis–NIR absorption spectra, absorption property of Sc:Yb:Tm:LiNbO₃ crystals is improved by doping Sc³⁺ ions. Additionally, the Sc:Yb:Tm:LiNbO₃ crystals can be pumped by commercially available high power AlGaAs LDs.

Original language	English
Article number	1900176
Journal	Crystal Research and Technology
Volume	55
Issue number	6
DOIs	https://doi.org/10.1002/crat.201900176
State	Published - 1 Jun 2020
Externally published	Yes

Keywords

Sc:Yb:Tm:LiNbO crystals
UV–vis–NIR
distribution coefficient
dopant occupancy

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10.1002/crat.201900176

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@article{26782b29c4ac4b25b2dddecfc1caffaa,

title = "Dopant Occupancy and UV–Vis–NIR Spectroscopy of Sc:Yb:Tm:LiNbO3 in the 300–3000 nm Wavelength Range",

abstract = "A series of Sc:Yb:Tm:LiNbO3 crystals with variable Sc3+ (0, 1, 2, and 3 mol\%) concentration are grown by the Czochralski method. The effective distribution coefficients of Sc3+, Yb3+, and Tm3+ ions in the Sc:Yb:Tm:LiNbO3 crystals are determined by inductively coupled plasma atomic emission spectrometer. Sc3+ ions distribute uniformly in crystals when Sc3+ concentration reaches up to 3 mol\%. The influence of Sc3+ concentration on the dopant occupancy and defect structure of Sc:Yb:Tm:LiNbO3 crystals is investigated by IR transmission spectra. Threshold concentration of Sc3+ ions in Sc:Yb:Tm:LiNbO3 crystals is nearly 3 mol\%. By analyzing UV–vis–NIR absorption spectra, absorption property of Sc:Yb:Tm:LiNbO3 crystals is improved by doping Sc3+ ions. Additionally, the Sc:Yb:Tm:LiNbO3 crystals can be pumped by commercially available high power AlGaAs LDs.",

keywords = "Sc:Yb:Tm:LiNbO crystals, UV–vis–NIR, distribution coefficient, dopant occupancy",

author = "Li Dai and Yuning Wang and Ruirun Chen and Shunxiang Yang and Xianbo Han and Chunrui Liu and Yu Shao",

note = "Publisher Copyright: {\textcopyright} 2020 WILEY-VCH Verlag GmbH \& Co. KGaA, Weinheim",

year = "2020",

month = jun,

day = "1",

doi = "10.1002/crat.201900176",

language = "英语",

volume = "55",

journal = "Crystal Research and Technology",

issn = "0232-1300",

publisher = "John Wiley \& Sons Inc.",

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TY - JOUR

T1 - Dopant Occupancy and UV–Vis–NIR Spectroscopy of Sc:Yb:Tm:LiNbO3 in the 300–3000 nm Wavelength Range

AU - Dai, Li

AU - Wang, Yuning

AU - Chen, Ruirun

AU - Yang, Shunxiang

AU - Han, Xianbo

AU - Liu, Chunrui

AU - Shao, Yu

PY - 2020/6/1

Y1 - 2020/6/1

N2 - A series of Sc:Yb:Tm:LiNbO3 crystals with variable Sc3+ (0, 1, 2, and 3 mol%) concentration are grown by the Czochralski method. The effective distribution coefficients of Sc3+, Yb3+, and Tm3+ ions in the Sc:Yb:Tm:LiNbO3 crystals are determined by inductively coupled plasma atomic emission spectrometer. Sc3+ ions distribute uniformly in crystals when Sc3+ concentration reaches up to 3 mol%. The influence of Sc3+ concentration on the dopant occupancy and defect structure of Sc:Yb:Tm:LiNbO3 crystals is investigated by IR transmission spectra. Threshold concentration of Sc3+ ions in Sc:Yb:Tm:LiNbO3 crystals is nearly 3 mol%. By analyzing UV–vis–NIR absorption spectra, absorption property of Sc:Yb:Tm:LiNbO3 crystals is improved by doping Sc3+ ions. Additionally, the Sc:Yb:Tm:LiNbO3 crystals can be pumped by commercially available high power AlGaAs LDs.

AB - A series of Sc:Yb:Tm:LiNbO3 crystals with variable Sc3+ (0, 1, 2, and 3 mol%) concentration are grown by the Czochralski method. The effective distribution coefficients of Sc3+, Yb3+, and Tm3+ ions in the Sc:Yb:Tm:LiNbO3 crystals are determined by inductively coupled plasma atomic emission spectrometer. Sc3+ ions distribute uniformly in crystals when Sc3+ concentration reaches up to 3 mol%. The influence of Sc3+ concentration on the dopant occupancy and defect structure of Sc:Yb:Tm:LiNbO3 crystals is investigated by IR transmission spectra. Threshold concentration of Sc3+ ions in Sc:Yb:Tm:LiNbO3 crystals is nearly 3 mol%. By analyzing UV–vis–NIR absorption spectra, absorption property of Sc:Yb:Tm:LiNbO3 crystals is improved by doping Sc3+ ions. Additionally, the Sc:Yb:Tm:LiNbO3 crystals can be pumped by commercially available high power AlGaAs LDs.

KW - Sc:Yb:Tm:LiNbO crystals

KW - UV–vis–NIR

KW - distribution coefficient

KW - dopant occupancy

UR - https://www.scopus.com/pages/publications/85082930633

U2 - 10.1002/crat.201900176

DO - 10.1002/crat.201900176

M3 - 文章

AN - SCOPUS:85082930633

SN - 0232-1300

VL - 55

JO - Crystal Research and Technology

JF - Crystal Research and Technology

IS - 6

M1 - 1900176

ER -

Dopant Occupancy and UV–Vis–NIR Spectroscopy of Sc:Yb:Tm:LiNbO₃ in the 300–3000 nm Wavelength Range

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Keywords

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