Abstract
We report the domain structure and ferroelectric properties of a 32 nm-thick Bi0.9Sm0.1FeO3 film epitaxially grown on a LaAlO3 (LAO) substrate. This film exhibits a monoclinic Mc phase, with its monoclinic distortion and anisotropy of in-plane (IP) lattice parameters being both smaller than those of pure BiFeO3 (BFO) grown on LaAlO3. Polarization hysteresis loops measured using a quasi-planar capacitor show an in-plane polarization up to 30 C/cm2. Piezoresponse force microcopy demonstrates that a 180 in-plane polarization switching accompanied by a 90 domain wall rotation takes place after electric poling. First-principles calculations suggest the differences between highly strained Sm-substituted and pure BiFeO3.
| Original language | English |
|---|---|
| Article number | 222904 |
| Journal | Applied Physics Letters |
| Volume | 99 |
| Issue number | 22 |
| DOIs | |
| State | Published - 28 Nov 2011 |
| Externally published | Yes |
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